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Cyclopeptidic Constituents from Arenaria oreophila J. D. Hooker (Caryophyllaceae)
作者姓名:Ai-Qun  Jia  Ning-Hua  Tan  Jun  Zhou
作者单位:State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, the Chinese Academy of Sciences, Kunming 650204, Yunnan, China
基金项目:Supported by the Yunnan Provincial Natural Science Foundation of China (2001B055M).
摘    要:To further investigate the cyclopeptldes of the Caryophyllaceae family, two new cyclopeptldes, named Arenarlphilin E (compound 1) and Arenariphilin F (compound 2), were obtained from Arenaria oreophUe J. D. Hooker using some Isolation methods, e. g. normal and reverse silica gel. By detailed spectroscopic analysis, such as FAB^+-MS, 1 D NMR, 2D NMR, the structures of Arenariphilin E (compound 1) and Arenariphilln F (compound 2) were determined as cyclo(lle^1-Gly-Val^1-Ala-Leu-lle^3-lle^2-Val^2-Pro) and cyclo(Pro^2-Pro^1-Gly^2-lle-Val-Leu-Gly^1-AiaThr- Gly^3), respectively.

关 键 词:鹅不食属  石竹科  植物学  研究方法
收稿时间:2005-09-07
修稿时间:2005-09-072006-03-11

Cyclopeptidic Constituents from Arenaria oreophila J. D. Hooker (Caryophyllaceae)
Authors:Ai-Qun Jia  Ning-Hua Tan  Jun Zhou
Institution:(State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, the Chinese Academy of Sciences;, Kunming 650204, Yunnan, China)
Abstract:To further investigate the cyclopeptides of the Caryophyllaceae family, two new cyclopeptides, named Arenariphilin E (compound 1) and Arenariphilin F (compound 2), were obtained from Arenaria oreophila J. D. Hooker using some isolation methods, e. g. normal and reverse silica gel. By detailed spectroscopic analysis, such as FAB+‐MS, 1D NMR, 2D NMR, the structures of Arenariphilin E (compound 1) and Arenariphilin F (compound 2) were determined as cyclo(Ile1‐Gly‐Val1‐Ala‐Leu‐Ile3‐Ile2‐Val2‐Pro) and cyclo(Pro2‐Pro1‐Gly2‐Ile‐Val‐Leu‐Gly1‐Ala‐Thr‐ Gly3), respectively. (Managing editor: Wei Wang)
Keywords:Arenaria oreophila  Arenariphilin E  Arenariphilin F  Caryophyllaceae  Cyclopeptide  
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