Cyclopeptidic Constituents from Arenaria oreophila J. D. Hooker (Caryophyllaceae) |
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作者姓名: | Ai-Qun Jia Ning-Hua Tan Jun Zhou |
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作者单位: | State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, the Chinese Academy of Sciences, Kunming 650204, Yunnan, China |
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基金项目: | Supported by the Yunnan Provincial Natural Science Foundation of China (2001B055M). |
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摘 要: | To further investigate the cyclopeptldes of the Caryophyllaceae family, two new cyclopeptldes, named Arenarlphilin E (compound 1) and Arenariphilin F (compound 2), were obtained from Arenaria oreophUe J. D. Hooker using some Isolation methods, e. g. normal and reverse silica gel. By detailed spectroscopic analysis, such as FAB^+-MS, 1 D NMR, 2D NMR, the structures of Arenariphilin E (compound 1) and Arenariphilln F (compound 2) were determined as cyclo(lle^1-Gly-Val^1-Ala-Leu-lle^3-lle^2-Val^2-Pro) and cyclo(Pro^2-Pro^1-Gly^2-lle-Val-Leu-Gly^1-AiaThr- Gly^3), respectively.
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关 键 词: | 鹅不食属 石竹科 植物学 研究方法 |
收稿时间: | 2005-09-07 |
修稿时间: | 2005-09-072006-03-11 |
Cyclopeptidic Constituents from Arenaria oreophila J. D. Hooker (Caryophyllaceae) |
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Authors: | Ai-Qun Jia Ning-Hua Tan Jun Zhou |
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Institution: | (State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, the Chinese Academy of Sciences;, Kunming 650204, Yunnan, China) |
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Abstract: | To further investigate the cyclopeptides of the Caryophyllaceae family, two new cyclopeptides, named Arenariphilin E (compound 1) and Arenariphilin F (compound 2), were obtained from Arenaria oreophila J. D. Hooker using some isolation methods, e. g. normal and reverse silica gel. By detailed spectroscopic analysis, such as FAB+‐MS, 1D NMR, 2D NMR, the structures of Arenariphilin E (compound 1) and Arenariphilin F (compound 2) were determined as cyclo(Ile1‐Gly‐Val1‐Ala‐Leu‐Ile3‐Ile2‐Val2‐Pro) and cyclo(Pro2‐Pro1‐Gly2‐Ile‐Val‐Leu‐Gly1‐Ala‐Thr‐ Gly3), respectively. (Managing editor: Wei Wang) |
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Keywords: | Arenaria oreophila Arenariphilin E Arenariphilin F Caryophyllaceae Cyclopeptide |
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