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13C NMR spectral analysis of grindelane diterpenoid acids
Authors:Manuel González Sierra  María I. Colombo  Marta E. Zudenigo  Edmundo A. Rúveda
Affiliation:Instituto de Química Orgánica de Síntesis (CONICET-UNR), Facultad de Ciencias Básicas, Suipacha 531, 2000 Rosario, Argentina
Abstract:The 13C NMR spectra of methyl grindelate and some of its derivatives were recorded and the signals assigned. Based on these assignments and on a comparison with previously reported data, information regarding the structures and stereochemistry of the products under study was obtained.
Keywords:grindelane diterpenoid acids  methyl grindelate  methyl grindelate epoxide  6α-hydroxygrindelic acid  6α-hydroperoxygrindelic acid  solidagenone  6α-solidagenol  6β-solidagenol.
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