Noroleanane saponins from Celmisia petriei |
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Authors: | Daryl D Rowan Roger H Newman |
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Institution: | Applied Biochemistry and Chemistry Divisions Department of Scientific and Industrial Research, Palmerston North and Petone, New Zealand |
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Abstract: | Two biologically active noroleanane saponins from Celmisia petriei are identified as 3-O-(α-l-arabinopyranosyl (1 → 6)-β-d-glucopyranosyl (1 → 2)-α-l-arabinopyranosyl), 2β,17,23-trihydroxy-28-norolean-12-en-16-one and its 2″-O-acetyl derivative. 13C NMR and T1 measurements allowed the determination of the sugar sequence and the majority of the linkage positions, but gave ambiguous results for the inner arabinose sugar. The structure of camellenodiol is revised to 3β,17-dihydroxy-28-norolean-12-en-16-one. |
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Keywords: | Compositae noroleanane saponins antinutrients spin-lattice relaxation times camellenodiol |
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