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NO formation during agricultural straw combustion
Authors:Ren Qiangqiang  Zhao Changsui  Duan Lunbo  Chen Xiaoping
Affiliation:a School of Energy and Environment, Southeast University, Nanjing 210096, China
b Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, China
Abstract:NO formation during combustion of four typical kinds of straw (wheat straw, rice straw, cotton stalk and corn stalk) which belong to soft straw and hard straw was studied in a tubular quartz fixed bed reactor under conditions relevant to grate boiler combustion. Regarding the real situation in biomass fired power plants in China, NO formation from blended straw combustion was also investigated. Nitrogen transfer during blended straw pyrolysis was performed using a thermogravimetric analyzer (TGA) coupled with a Fourier transform infrared (FTIR) spectrometer. The results show that NO conversion for the four straws during combustion is distinctive. Over 70% fuel-N converts into NO for cotton stalk, while only 37% for wheat straw under the same condition. When wheat straw and cotton stalk were mixed, N-NO conversion increases. The limestone addition promotes NO emission during cotton stalk combustion. The presence of SO2 in atmosphere suppresses NO formation from straw combustion.
Keywords:Straw   Blended straw   Combustion   Pyrolysis   NO formation
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