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Ionic iridium-gold and rhodium-gold perfluorobenzenethiolato binuclear complexes: syntheses and solution behavior |
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| Authors: | Juventino J. Garcia, Marí a L. Hern ndez, Hugo Torrens, Atilano Gutierrez,Federico del Rí o |
| Affiliation: | a Departamento de Química Inorgánica, Facultad de Química, Universidad Nacional Autónoma de México, 04510, Mexico, DF, Mexico b Instituto de Química, Universidad Nacional Autónoma de México, 04510, Mexico, DF, Mexico |
| Abstract: | By reacting [(C5Me5)M(SRF)2] (forM = Ir, Rf = C6F5 (1a) or C6F4H-p (1b); for M = Rh, Rf = C6F5 (2a) or C6F4H-p (2a)) in toluene with Na[AuCl4], ionic binuclear compounds with the general formula [(C5Me5)M(μ-SRF)2AuCl2]Cl for M = Ir, R = C6F5 (3a) or C6F4H-p (3a); for M = Rh, RF = C6F5 (4a) or C6F4H-p (4b) can be obtained, together with small amounts of [(C5Me5)2Rh2(μ-SRF)(μ-Cl)2]Cl (RF = C6F5 (5a) or C6F4H-p (5b)) as by-products when 2a and 2b were used. |
| Keywords: | Iridium complexes Rhodium complexes Gold complexes Thiolato complexes Binuclear complexes Pentamethylcyclopentadienyl |
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