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Redox reactions via vanadium-induced electron transfer
Authors:Hirao T
Institution:Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Japan.
Abstract:One-electron reduction and oxidation induced by vanadium complexes are demonstrated to be useful in oxidative and reductive transformations of carbonyl compounds. The redox interaction between vanadium complexes and redox-active ligands is achieved with coenzyme PQQ and polyanilines that afford the corresponding redox systems.
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