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Stopped flow microcalorimetry without adiabatic compression: Application to reactions with half-lives between 3 and 50 ms |
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| Authors: | Patrick Bowen Bohdan Balko Keith Blevins Robert L Berger Harry P Hopkins |
| Institution: | 1. Laboratory of Technical Development, National Heart, Lung and Blood Institute, National Institutes of Health, Bethesda, Maryland 20205 USA;2. Department of Chemistry, Georgia State University, Atlanta, Georgia 30303 USA |
| Abstract: | A stopped flow apparatus with a thermal sensor has been developed with an uptake syringe mechanically coupled to a set of driving syringes that alleviates the pressure-induced temperature change previously observed at the point of stopping the flow. With this effect eliminated we can now study reactions with total reaction times that are close to the response time of the thermistor (7 ms). |
| Keywords: | To whom correspondence should be addressed |
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