Thermal deamination kinetics of the nickel-containing chabazite-like aluminophosphate, Ni(NH2-CH2-CH2-NH2)2(AlPO4)6(OH)2, deposition of nanocrystalline NiO particles |
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Authors: | Nevenka Rajic Djordje Stojakovic |
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Institution: | a Faculty of Technology and Metallurgy, University of Belgrade, 11000 Belgrade, Serbia b Jozef Stefan Institute, Jamova 39, 1000-Ljubljana, Slovenia |
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Abstract: | Thermogravimetrical analysis has been used to study the kinetics of thermal deamination of bis(ethylenediamine)nickel(II)-containing aluminophosphate (Ni-CHA) which is a precursor of nickel(II)-containing chabazite-like AlPO4-34. The deamination occurs as a single-step kinetic process which is best described by the contracting cylinder model. The obtained activation energy of 200 kJ/mol is mainly a reflection of the strong Ni-N coordination bond. The thermal decomposition of Ni-CHA results in the deposition of crystalline NiO particles homogeneously dispersed in the AlPO4-34 lattice. Average particle size was found to be about 5 nm. The study confirms that the thermal decomposition of amine complexes of Ni(II) encapsulated inside the microporous aluminophosphate host can be a suitable method for obtaining fine nano-oxide particles. |
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Keywords: | AlPO4-34 Chabazite-like Nano-oxide Decomposition kinetics TEM |
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