Ruthenium(VI) and osmium(VI) nitrido complexes with halogenated phenoxide and thiophenoxide ligands |
| |
| Authors: | Ngai-Man Lam Chun-Sing Lai Qian-Feng Zhang Wa-Hung Leung |
| |
| Institution: | a Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, PR China
b Department of Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui 243002, PR China |
| |
| Abstract: | Treatment of Bun4N]Ru(N)Cl4] with Na(OR) afforded Bun4N]Ru(N)(OR)4] (R = C6F5 (1), C6F4H (2), C6Br5 (3)), whereas that with Bun4N]Os(N)Cl4] gave Bun4N]Os(N)(OR)3Cl] (R = C6F5 (4), C6F4H (5), C6Br5 (6)). Treatment of Bun4N]M(N)Cl4] with Na(SC6F4H) and Na(Sxyl) (xyl = 2,6-dimethylphenyl) afforded Bun4N]M(N)(SC6F4H)4] (M = Ru (7), Os (8)) and Bun4N]M(N)(Sxyl)4] (M = Ru (9), Os (10)), respectively. The crystal structures of compounds 1, 6 and 9 have been determined. |
| |
| Keywords: | Ruthenium Osmium Nitrido Phenoxide Thiophenoxide |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
