Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex |
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Authors: | Sakthivel Kandaiah |
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Affiliation: | Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, 70569 Stuttgart, Germany |
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Abstract: | We present the electrochemical synthesis by galvanostatic electro-oxidation method and single crystal structure determination of a complex of silver(II) with a macrocyclic N donor ligand crystallized with hexafluorophosphate anions. The crystal structure analysis showed a penta-coordinated environment of silver(II) and displacement of the metal centre from the rectangular planar configuration of the macrocyclic N donor which is due to axial coordination by a solvent acetonitrile molecule. Both PF6− anions were modelled with two-fold disorder. |
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Keywords: | Silver Higher oxidation state Tetramethyltetraazacyclotetradecane Electrochemical synthesis Solvent coordination, hexafluorophosphate |
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