A 3D chiral supramolecular framework of Cu(II): Synthesis, structure and magneto-structural correlations |
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Authors: | KL Gurunatha Golam Mostafa Tapas Kumar Maji |
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Institution: | a Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, Karnataka, India b Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, Karnataka, India c Department of Physics, Jadavpur University, Jadavpur, Kolkata 700 032, India |
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Abstract: | A metal-organic coordination chain of Cu(II), viz {Cu(Hbtc)(NH3)4](H2O)}n (1) (btc = benzenetricarboxylate) has been synthesized and structurally characterized. The sky blue single crystals of 1 were grown by the dissolution of the as-synthesized insoluble product obtained from the reaction of Cu(II), H3btc and 4,4′-bipy in aqueous NH3 solution. Structural determination reveals that 1 crystallizes chiral P212121 space group and 1D coordination chain of Cu(II) bridged by the Hbtc linker. 1D chains are H-bonded via the guest water molecules forming a 2D sheet like structure and 2D sheets through π-π and N-H···O H-bonding interactions produce a 3D supramolecular framework with 1D water filled channels along the a-axis. Temperature dependent magnetic measurement exhibits weak antiferromagnetic intrachain interaction between Cu(II) centers through the Hbtc linker with J = −0.17 cm−1 and g = 2.01 and at low temperature interchain ferromagnetic interaction is predominates. The dominant antiferromagnetic interaction is supported by the DFT calculations. |
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Keywords: | Cu(II) complex Supramolecular framework Chiral network Antiferromagnetic interaction Ferromagnetic interaction DFT calculation |
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