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Adsorption of Methylene Blue Dye on Pure and Carbonized Water Weeds
Authors:Timi Tarawou  Michael Horsfall Jr
Institution:Department of Pure and Industrial Chemistry , University of Port Harcourt , Port Harcourt, Nigeria
Abstract:The influence of process variables in batch adsorption has been used to assess the removal of methylene blue dye from aqueous solution using pure and carbonized biomasses of water hyacinth and water spinach. Dried leaves of the water weeds were carbonized at temperature up to 750°C. The optimum removal of dye was achieved at pH 10, 30°C, and 55 min at a dye concentration of 10 mg/L. In an attempt to describe the adsorption process, the equilibrium isotherm for each adsorbent was determined using Langmuir and Freundlich adsorption isotherm models. Maximum adsorption capacities based on the Langmuir model for pure and carbonized water hyacinth were (mg/g) 7.05 and 2.07, respectively, whereas those of pure and carbonized water spinach were 1.25 and 5.32, respectively. It was observed that the equilibrium data were well fit by both the Freundlich and Langmuir isotherms as R 2 > .97. This study demonstrates that the two waterweeds are effective, environmentally friendly, and inexpensive biomaterials for the removal of color from industrial effluents.
Keywords:adsorption  bioremediation  dyes and pigments  methylene blue  waste water treatment  water weeds
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