Oxidation of 4-chloroaniline catalyzed by human myeloperoxidase |
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| Authors: | A.R.J. Bakkenist H. Plat R. Wever |
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| Affiliation: | Laboratory of Biochemistry, B.C.P. Jansen Institute, University of Amsterdam, Plantage Muidergracht 12, 1018 TV Amsterdam, The Netherlands |
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| Abstract: | The incubation of 4-chloroaniline with H2O2 and myeloperoxidase results in the formation of at least 10 products. Possibly some structures with high complexity, like 4,4′-dichloroazobenzene, are present; however, no 4-chloronitrosobenzene is detectable. This result contrasts with the oxidation of 4-chloroaniline catalyzed by chloroperoxidase, which only yields 4-chloronitrosobenzene. |
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