Optically active molecule-based magnets: enantioselective self-assembling, optical, and magnetic properties. |
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| Authors: | M Gruselle R Andres B Malezieux M Brissard C Train M Verdaguer |
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| Institution: | Chimie Inorganique et Matériaux Moléculaires CIM2 Unité CNRS 7071, Université Pierre et Marie Curie, Paris, France. gruselle@ccr.jussieu.fr |
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| Abstract: | In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic Cr-Mn] networks Delta Cr(III) Delta Mn(II)(ox)(3)]Delta Ru(II)(bpy)(3)]ClO(4)](n)1 - Delta, Lambda Cr(III)Lambda Mn(II)(ox)(3)]Lambda Ru(II) (bpy)(3)]ClO(4)](n) 1 - Lambda and Delta Cr(III)Delta Mn(II)(ox)(3)]Delta Ru(II)(bpy)(2)p p y]](n) 2 - Delta,Lambda Cr(III)Lambda Mn(II)(ox)(3)]Lambda Ru(II)(bpy)(2)ppy]](n) 2 - Lambda (ox = oxalate, bpy = bipyridine, ppy = phenyl-pyridine). |
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