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Carbohydrate functionalization using cationic iron carbonyl complexes |
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| Authors: | Bergh Anders Gradén Henrik Pera Núria Parera Olsson Thomas Nilsson Ulf J Kann Nina |
| Institution: | 1. Organic Chemistry, Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden;2. AstraZeneca R&D Mölndal, SE-43183 Mölndal, Sweden;3. Organic Chemistry, Lund University, PO Box 124, SE-22100 Lund, Sweden |
| Abstract: | Cationic iron carbonyl cyclohexadiene complexes were employed in the derivatization of the 3-OH position of unprotected and protected methyl beta-D-galactopyranosides using two different approaches, giving access to galactopyranosides with an aromatic or cyclohexadienoic functionality in this position. |
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