Theory of intermolecular electron transfer in nanoscale biological structures |
| |
Authors: | P M Krasilnikov |
| |
Institution: | 1.Biological Faculty,Moscow State University,Moscow,Russia |
| |
Abstract: | Macromolecular biological systems performing directed electron transfer are nano-sized structures. The distance between carrier
molecules (cofactors), which represent practically isolated electron localization centers, reaches tens of angstroms. The
electron transfer theory based on the concept of delocalized electron states, which is conventionally used in biophysics,
is unable to adequately interpret the results of concrete observations in many cases. On the basis of the theory of electronic
transitions in the case of localized states, developed in the physics of disordered matter, a mechanism of long-distance electron
transfer in biological systems is suggested. The molecular relaxation of the microenvironment of electron localization centers
that accompanies the electron transfer process is also considered. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|