Lambertellol C, a labile and novel biosynthetic congener of lambertellols A and B |
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| Authors: | Murakami Takanori Sasaki Akane Fukushi Eri Kawabata Jun Hashimoto Masaru Okuno Toshikatsu |
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| Affiliation: | Faculty of Agriculture and Life Science, Hirosaki University, 3-Bunkyo-cho, Hirosaki 036-8561, Japan. |
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| Abstract: | Lambertellol C (1), a labile biosynthetic congener of lambertellols A and B, was isolated from a fermentation broth of Lambertella sp. 1346 based on the diagnostic isotope patterns in the mass spectrum of a highly labeled sample. The CD spectrum of 1 indicated that this lambertellol analogue exists as a racemate. The mechanism for this racemization is discussed. |
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