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Bioluminescence — the biochemistry of photogens and photagogika
Authors:Frank H. Johnson  Osamu Shimomura
Abstract:The present trend emphasizes the definitive chemistry of photogens, such as specific luciferins, and of photagogika (the actual light-emitters) rather than indirect evidence concerning components of bioluminescent systems as has been practices for almost a century, resulting in many misleading hypotheses. Recent advances indicate that, contrary to earlier conclusions, chemically identical components characterize divers types of bioluminescent organisms and that the r route to light emission probably always involves a hydroperoxide that, at least in some instances, leads to formation of a dioxytenone ring before decomposition.
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