Synthesis of fagopyritols A1 and B1 from D-chiro-inositol |
| |
| Authors: | Cid M Belén Alfonso Francisco Martín-Lomas Manuel |
| |
| Institution: | Grupo de Carbohidratos, Instituto de Investigaciones Quimicas, CSIC, Américo Vespucio s/n, Isla de La Cartuja, 41092 Sevilla, Spain. |
| |
| Abstract: | Fagopyritol A1 (3-O-alpha-d-galactopyranosyl-d-chiro-inositol) and fagopyritol B1 (2-O-alpha-d-galactopyranosyl-d-chiro-inositol) have been synthesized by glycosylation of the diequatorial diol 1,4,5,6-tetra-O-benzoyl-d-chiro-inositol, readily obtained from d-chiro-inositol, with 2,3,4,6-tetra-O-benzyl-d-galactopyranosyl trichloroacetimidate. |
| |
| Keywords: | Regioselective glycosylation Glycosyl inositols Insulin mimetics |
| 本文献已被 ScienceDirect PubMed 等数据库收录！ |
|
