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6-Demethylvignafuran as a phytoalexin of Tetragonolobus maritimus
Authors:John L. Ingham  Paul M. Dewick
Affiliation:Phytochemical Unit, Department of Botany, University of Reading, Reading RG6 2AS, England;Department of Pharmacy, University of Nottingham, Nottingham NG7 2RD, England
Abstract:A phytoalexin isolated from the fungus-inoculated leaves of Tetragonolobus maritimus has been identified as 6-demethylvignafuran (2-[4-hydroxy-2-methoxyphenyl]-6-hydroxybenzofuran). The synthesis of 6-demethyl-vignafuran and two isomeric benzofurans is described. The presence of 3,9-dihydroxypterocarp-6a-ene in T. maritimus is also reported.
Keywords:Leguminosae  Loteae  2-arylbenzo-furan  pterocarpene  phytoalexin  antifungal activity  isoflavonoid  benzofuran synthesis.
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