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Glycosides of tricetin methyl ethers as chemosystematic markers in Stachys subgenus Betonica
Authors:Marin Petar D  Grayer Renée J  Grujic-Jovanovic Slavica  Kite Geoffrey C  Veitch Nigel C
Institution:Jodrell Laboratory, Royal Botanic Gardens, Kew, Richmond, Surrey TW9 3AB, UK.
Abstract:Nine species from the genus Stachys L. representing subgenera Stachys and Betonica were surveyed for flavonoid glycosides by means of HPLC coupled to diode-array detection and LC-APCI-MS. Those species belonging to subgenus Betonica were characterised by the presence of glycosides of tricetin methyl ethers, including a new derivative, which was isolated from S. scardica Griseb. and identified as tricetin 3',4',5' -trimethyl ether 7-O-beta-glucopyranoside by spectroscopic methods. This type of flavonoid was absent from species belonging to subgenus Stachys and can be considered as a chemosystematic marker for subgenus Betonica.
Keywords:Stachys  Betonica  Lamiaceae  Flavonoid glycosides  Tricetin 3  4  5-trimethyl ether 7-O-β-glucopyranoside  Tricetin derivatives  Chemosystematics
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