Stereoselective synthesis and X-ray structure of 1-(4-O-benzyl-1,5-anhydro-2,3-dideoxy-D-arabino-hex-1-enitol-3-yl )-4-me thoxy-1H-pyrimidin-2-one |
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| Authors: | Sugimura H |
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| Institution: | Faculty of Education and Human Science, Yokohama National University, Japan. sugimura@edhs.ynu.ac.jp |
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| Abstract: | The intramolecular glycosylation of a 6-O-(4-methoxypyrimidin-2-yl) derivative of phenyl 2,3-didehydrohex-2-eno-1-thiopyranoside afforded 3-deoxy-3-(4-methoxypyrimidin-2-on-1-yl)glycal as the major product in a stereoselective manner. The isolated 3'-deoxyglycal nucleoside was characterized by X-ray and NMR spectral analyses. |
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