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New germacranolides and other sesquiterpene lactones from Dicoma species
Authors:Ferdinand Bohlmann  Pahup Singh  Jasmin Jakupovic
Affiliation:Institute for Organic Chemistry, Technical University of Berlin, D-1000 Berlin 12, West Germany
Abstract:Two subspecies of Dicoma anomala afforded, in addition to known compounds, an eudesmanolide, a guaianolide and four germacranolides, the latter being closely related 8, 12-lactones. D. schinzii gave three new germacranolides and D. zeyheri a pair of isomeric acetylenic compounds. The structures were elucidated by highfield 1H NMR spectroscopy. The chemotaxonomic situation of this genus is discussed briefly.
Keywords:Compositae  Mutisieae  sesquiterpene lactones  germacranolides  eudesmanolide  guaianolide  acetylenic compounds.
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