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Isolation and characterization of a 3,4-pyruvic acetalated-d-galactose-containing oligosaccharide obtained from the capsular polysaccharide of Klebsiella K33 by Smith Degradation
Authors:Arepalli S Rao  Elvin A Kabat  Noel F Whittaker  Bo Nilsson  David A Zopf  Wolfgang Nimmich
Institution:1. Departments of Microbiology, Human Genetics and Development, and Neurology, and the Cancer Center/Institute for Cancer Research, Columbia University College of Physicians and Surgeons, New York, NY 10032 U.S.A.
Abstract:The capsular polysaccharide of Klebsiella K33 was subjected to Smith degradation, and an oligosaccharide-alditol, RL 0.8, was isolated. The purified oligosaccharide-alditol was characterized by sugar and methylation analyses, and by mass spectrometry as the permethylated derivative, and found to have the following structure.
Keywords:
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