Isolation and characterization of a 3,4-pyruvic acetalated-d-galactose-containing oligosaccharide obtained from the capsular polysaccharide of Klebsiella K33 by Smith Degradation |
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Authors: | Arepalli S Rao Elvin A Kabat Noel F Whittaker Bo Nilsson David A Zopf Wolfgang Nimmich |
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Institution: | 1. Departments of Microbiology, Human Genetics and Development, and Neurology, and the Cancer Center/Institute for Cancer Research, Columbia University College of Physicians and Surgeons, New York, NY 10032 U.S.A. |
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Abstract: | The capsular polysaccharide of Klebsiella K33 was subjected to Smith degradation, and an oligosaccharide-alditol, RL 0.8, was isolated. The purified oligosaccharide-alditol was characterized by sugar and methylation analyses, and by mass spectrometry as the permethylated derivative, and found to have the following structure. |
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