The configuration,solvatochromism and metallo‐responses of two novel cyano‐containing oligo(phenylene‐vinylene) derivatives |
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| Authors: | Jing Lv Xiaodong Yin Haiyan Zheng Yongjun Li Yuliang Li Daoben Zhu |
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| Institution: | 1. CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry Chinese Academy of Sciences, Beijing 100190, People's Republic of China;2. Graduate School of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, 100190, People's Republic of China |
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| Abstract: | Two novel cyano‐containing oligo(phenylenevinylene) (OPV) derivatives have been designed and synthesized. Photophysical and sensing properties of the two compounds were studied. Such studies reveal the intramolecular charge transfer process between cyano groups and OPV core. The results showed that the alkyl difference of substituted OPV leads to the changes of molecular configuration and metallo‐response of two compounds. Copyright © 2010 John Wiley & Sons, Ltd. |
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| Keywords: | cyano charge transfer twisted configuration solvatochromism sensor |
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