A new tricarbonyl fac-[M(acac)(isc)(CO)3] complex (M = Re, Tc) with acetylacetonate (acac) and isocyanide (isc) in a 2+1 combination |
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Authors: | Marina Sagnou Charalambos Triantis Aris Terzis Maria Pelecanou Minas Papadopoulos |
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Institution: | a Institute of Biology, National Centre for Scientific Research “Demokritos”, 15310 Athens, Greece b Institute of Radioisotopes and Radiodiagnostic Products, National Centre for Scientific Research “Demokritos”, 15310 Athens, Greece c Institute of Materials Science, National Centre for Scientific Research “Demokritos”, 15310 Athens, Greece |
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Abstract: | The synthesis and characterization of the neutral 2+1 mixed ligand complex fac-Re(CO)3(acac)(isc) (4) with acetylacetonate (acac) as the bidentate ligand and an isocyanide (the isocyanocyclohexane, isc) as the monodentate ligand is described. The synthesis of 4 proceeds through the intermediate formation of the fac-Re(acac)(H2O)(CO)3 precursor complex 2. Complex 4 was characterized by elemental analysis, spectroscopic methods, and X-ray crystallography showing a distorted octahedral arrangement of the ligands around Re. At technetium-99m level, the corresponding fac-99mTc(acac)(isc)(CO)3 complex 5 was obtained in high yield by reacting the fac-99mTc(acac)(H2O)(CO)3 precursor complex 3 with isocyanocyclohexane and its structure was established by chromatographic comparison with the prototypic rhenium complex using high performance liquid chromatography. |
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Keywords: | Rhenium Technetium-99m Tricarbonyl complexes Acetylacetone Isocyanide |
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