Syntheses of some new methylcyclopentadienylmolybdenum complexes: Characterizations, crystal structures and comparisons with related complexes |
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| Authors: | Thiruvengadam Munisamy Andreas Franken |
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| Institution: | Department of Chemistry, Baylor University, One Bear Place #97348, Waco, TX 76798, USA |
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| Abstract: | As part of a long-term study of the substitution reactions of piano-stool type cyclopentadienylmetal carbonyl complexes, several new methylcyclopentadienylmolybdenum compounds have been prepared and characterized by methods including IR spectroscopy, electrospray ionization mass spectrometry and X-ray crystallography. The complexes reported here include {Cp′Mo(CO)3}2I]BPh4, cis-Cp′Mo(CO)2(PPh3)I and Cp′Mo(CO)3(CH3CN)]BF4 (Cp′ = η5-C5H4CH3). In addition to their syntheses, comparisons are made between their IR spectroscopic and X-ray crystal structure data and those of similar complexes. |
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| Keywords: | Molybdenum complex Carbonyl complex Methylcyclopentadienyl complex X-ray crystal structure |
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