A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides |
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| Authors: | Jonathan F Hull |
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| Institution: | Yale University, Department of Chemistry, 225 Prospect St., New Haven, CT 06511, USA |
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| Abstract: | Ru(DMSO)4Cl2 is catalytically active for converting aldehydes to primary amides via oxime intermediates. This catalyst is readily available, and requires no additional ligands, a great simplification compared to previous work. A Ru(II)/(IV) mechanism is proposed. |
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| Keywords: | Beckmann rearrangement Aldoxime |
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