Unusual lithium coordinated platinum and rhodium hydride dimers |
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| Authors: | Brett D. Swartz |
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| Affiliation: | Department of Chemistry, University of Rochester, Rochester, NY 14627, USA |
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| Abstract: | Two unusual lithium coordinated binuclear platinum- and rhodium-hydride complexes [M(dippe)(H)]2·LiHBEt3 were synthesized and characterized by NMR spectroscopy and X-ray crystallography. Not only does the lithium ion interact with the metal hydrides, but also with the B-H bond of the borohydride. |
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| Keywords: | Platinum complexes Rhodium complexes Hydride complexes X-ray crystal structures |
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