Triazole based cadmium(II) anionic framework with 2-dimensional helical channels: Ionic liquid induced synthesis |
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| Authors: | Kafeel Ahmad Siddiqui Gopal Krishna Mehrotra |
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| Institution: | a Department of Chemistry, Motilal Nehru National Institute of Technology, Allahabad 211004, UP, India
b Institut fuer Anorganische Chemie, J.-W.-Goethe-Universitaet, Max-von-Laue-Str.7, D-60438 Frankfurt/Main, Germany |
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| Abstract: | A novel 2D MOF material Cd2(AmTRZ)2·I3]·(R4N+)] (1; AmTRZ = 3-amino-1,2,4-triazole, R4N+ = tetraethylammonium), with an anionic skeleton has been hydrothermally synthesized in presence of an ionic liquid, tetraethylammonium hydroxide. 1 is endowed with large helical porous channels and two cadmium metal centers with different coordination environment around them besides showing presence of an unprecedentedly ordered extra-framework layer pattern of the encapsulated Et4N+ counter cations. |
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| Keywords: | Cadmium-triazolate Anionic MOF 2-D helical pores Ionic liquid |
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