Reactions of the fac-[Re(CO)3] and [ReO] moieties with substituted benzothiazoles |
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| Authors: | Irvin N. Booysen Peter Mayer |
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| Affiliation: | a Department of Chemistry, Nelson Mandela Metropolitan University, University Way, Summerstrand, 6031 Port Elizabeth, South Africa
b Department of Chemistry, Ludwig-Maximilians University, D-81377 Munich, Germany |
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| Abstract: | The reaction of 2-(2-aminophenyl)benzothiazole (Habt) with [Re(CO)5Br] led to the isolation of the rhenium(I) complex fac-[Re(Habt)(CO)3Br] (1). With trans-[ReOCl3(PPh3)2], the ligand Habt decomposed to form the oxofree rhenium(V) complex [Re(itp)2Cl(PPh3)] (2) (itp = 2-amidophenylthiolate). From the reaction of trans-[ReOBr3(PPh3)2] with 2-(2-hydroxyphenyl)benzothiazole (Hhpd) the complex [ReVOBr2(hpd)(PPh3)] (3) was obtained. Complexes 1-3 are stable and lipophilic. 1H NMR and infrared assignments, as well as the X-ray crystal structures, of the complexes are reported. |
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| Keywords: | Benzothiazoles derivatives fac-[Re(CO)3]+ ReO3+ Oxofree rhenium(V) |
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