Investigation of the solution behavior of tri-n-butylphosphine copper(I) and silver(I) acetates using P{H} NMR spectroscopy |
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| Authors: | Uwe Siegert |
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| Institution: | Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Chemie, Lehrstuhl für Anorganische Chemie, Straße der Nationen 62, 09111 Chemnitz, Germany |
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| Abstract: | 31P{1H} NMR spectra of metal-organic (nBu3P)mMO2CMe] (M = Cu, Ag; m = 1, 1.5, 2, 2.5, 3, 3.5, 4) have been studied in the temperature range of 308-178 K. Exchange parameters were determined for the appropriate silver(I) complexes. Possible ligand exchange mechanisms based on dissociative and associative processes are discussed. |
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| Keywords: | Copper(I) Silver(I) Acetate NMR spectroscopy Exchange parameters |
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