Synthesis and investigation of spectral and electrochemical properties of alkyl-substituted planar binuclear phthalocyanine complexes sharing a common naphthalene ring |
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Authors: | Tatiana V Dubinina Aleksey V Ivanov Stanislav A Trashin Larisa G Tomilova Nikolay S Zefirov |
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Institution: | a Chemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991 Moscow, Russia b Institute of Physiologically Active Compounds, 1 Severny Proezd, 142432 Chernogolovka, Moscow Region, Russia |
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Abstract: | Hexa-tert-butyl and dodeca-n-butyl-substituted planar binuclear phthalocyanines sharing a common naphthalene ring with Mg as a central metal were synthesized with high yields and characterized by UV/Vis spectra, luminescence spectra, NMR, electrochemical, and spectroelectrochemical measurements. On the base of these complexes, the metal-free phthalocyanine ligands and the series of binuclear phthalocyanine complexes of rare earth elements (REE) were synthesized.All compounds obtained revealed an intensive near IR-absorption reaching 855 nm for trinuclear phthalocyanine. A crucial increase in NMR spectra resolution was achieved by the addition of ethylene glycol as a disaggregating agent. Spectroelectrochemical measurements during oxidation showed reversible changes of absorbance at 709 and 800 nm. |
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Keywords: | Binuclear phthalocyanines UV/Vis spectroscopy Fluorescence spectroscopy Voltammetry Spectroelectrochemistry |
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