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New prenylated isoflavones and a prenylated dihydroflavonol from Millettia pachycarpa
Authors:Ashok K. Singhal  Ram P. Sharma  Gopalakrishna Thyagarajan  Werner Herz  Serengolam V. Govindan
Affiliation:1. Department of Organic Chemistry, Regional Research Laboratory, Jorhat—785006, Assam, India;2. Department of Chemistry, The Florida State University, Tallahassee, FL 32306, U.S.A.
Abstract:Extraction of Millettia pachycarpa Benth. gave 5,7,4′-trihydroxy-6,8-diprenylisoflavone (1a), 5,7,4′-trihydroxy-6,3′-diprenylisoflavone (2a), 5,7,3′,4′-tetrahydroxy-6,8-diprenylisoflavone (3a) and (2R, 3R)-5,4′-dihydroxy-8-prenyl-6″,6″-dimethylpyrano[2″,3″: 7,6]-dihydroflavonol (4a) whose structures were established by chemical transformations and spectroscopic means. Pectolinarigenin and salvigenin were isolated from Buddleia macrostachya Benth.
Keywords:Leguminosae  Lotodoideae  prenylated isoflavones  prenylated dihydroflavonols  Buddleiaceae  pectolinarigenin  salvigenin
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