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Polyacetylenes from the rabbitbrush,Chrysothamnus nauseosus
Authors:Allan F Rose  BA Butt  Tibor Jermy
Institution:1. Yakima Argricultural Research Laboratory, Yakima, WA 98902, U.S.A.
Abstract:Four new polyacetylenes, methyl Z,Z-10-acetoxymatricariate, methyl Z,Z-10-hydroxymatricariate, methyl 2(Z)-10-acetoxy-8,9-epoxydecen- 4,6-diynoate and methyl 2(Z)-10-hydroxy-8,9-epoxydecen-4,6-diynoate, were isolated from the composite Chrysothamnus nauseosus. These compounds are naturally-occurring antifeedants of the Colorado potato beetle. The assigned structures rest on their spectroscopic properties as well as chemical interconversions.
Keywords:Compositae  rabbitbrush  new polyacetylenes  insect antifeedant substances  isolation  structure determination
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