Ir spectra and conformational behavior of N-acetyl-(glycine,L-alanine,L-leucine)-N′-methylamides in chloroform |
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Authors: | Chalakkal I. Jose Anagha A. Belhekar Mangala S. Agashe |
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Abstract: | NH stretching bands of N-acetyl-(glycine, L -alanine, L -leucine)-N′-methylamides in dilute chloroform solution have shown that these dipeptides are present as a mixture of intramolecularly hydrogen-bonded five-membered ring species and nonhydrogen bonded species. Integrated absorption intensity measurements revealed that the concentration of the intramolecularly hydrogen bonded species decreased from 62% in glycine to 35% in the L -leucine derivatives. |
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