Metabolism of lignin-related compounds by Rhodococcus rhodochrous: bioconversion of anisoin |
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Authors: | V Andreoni S Bernasconi P Bestetti M Villa |
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Institution: | (1) Dipartimento di Valorizzazione e Protezione delle Risorse Agroforestali, Universitá di Torino, via Giuria 15, I-10126 Torino, Italy;(2) Dipartimento di Chimica Organica ed Industriale, Universitá di Milano, via Venezian 21, I-20 133 Milano, Italy;(3) Dipartimento di Genetica e Biologia dei Microrganismi, Universitá di Milano, via Celoria 26, I-20 133 Milano, Italy |
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Abstract: | Summary The ability of the nocardioform actinomycete Rhodococcus rhodochrous to metabolize selected lignin model compounds was studied. The compounds studied included cinnamic and ferulic acids and dimers possessing intermonomeric linkages that are characteristic of the lignin molecule. R. rhodochrous reduced the carbonyl group of anisoin, a 1,2-diarylethane (-1) structure to (1R,2R)-1,2-bis(4-methoxyphenyl)ethane-1,2-diol with an enantiomeric excess of .98%. Cleavage of 1,2-diarylethane and -O-4 structures by this strain could not be detected under our metabolic conditions.
Offprint requests to: V. Andreoni |
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