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Study on solvent extraction of propionic acid from simulated discharged water in vitamin B12 production by anaerobic fermentation
Authors:Kang Wang  Zhidong Chang  Yinchen Ma  Chao Lei  Jing Wang  Tingyu Zhu  Huizhou Liu  Yanjun Zuo  Xin Li
Institution:1. Laboratory of Green Process and Engineering, Laboratory of Separation Science and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, China;3. Graduate School of Chinese Academy of Agricultural Sciences, Beijing 100081, China
Abstract:The potential of recovering propionic acid from discharged water in vitamin B12 production by anaerobic fermentation was investigated in this paper. A primary amine, N1923, was used as the extractant, kerosene as diluter and n-octanol as modifier. The influences of the content of N1923 in the organic phase, the phase ratio and the pH of aqueous phase on the extraction yield of propionic acid were studied. The organic phase composition with the volume ratio was proposed of N1923:kerosene:n-octanol as 45:35:20. Under conditions of the phase ratio (o/w) as 1:4, the pH of aqueous phase of 3.0 and after 5 min extraction, the extraction yield of propionic acid can be over 97%.
Keywords:Primary amine  Propionic acid  Extraction  Wastewater
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