Optimization of H2SO4-catalyzed hydrothermal pretreatment of rapeseed straw for bioconversion to ethanol: Focusing on pretreatment at high solids content |
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Authors: | Xuebin Lu Yimin Zhang Irini Angelidaki |
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Institution: | 1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;2. Department of Environmental Engineering, Technical University of Denmark, Lyngby 2800, Denmark |
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Abstract: | A central composite design of response surface method was used to optimize H2SO4-catalyzed hydrothermal pretreatment of rapeseed straw, in respect to acid concentration (0.5–2%), treatment time (5–20 min) and solid content (10–20%) at 180 °C. Enzymatic hydrolysis and fermentation were also measured to evaluate the optimal pretreatment conditions for maximizing ethanol production. The results showed that acid concentration and treatment time were more significant than solid content for optimization of xylose release and cellulose recovery. Pretreatment with 1% sulfuric acid and 20% solid content for 10 min at 180 °C was found to be the most optimal condition for pretreatment of rapeseed straw for ethanol production. After pretreatment at the optimal condition and enzymatic hydrolysis, 75.12% total xylan and 63.17% total glucan were converted to xylose and glucose, respectively. Finally, 66.79% of theoretical ethanol yielded after fermentation. |
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Keywords: | Hydrothermal pretreatment H2SO4 Rapeseed straw Bioethanol |
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