A novel green enzymatic synthetic route of 2, 3-dihydroxybenzoic acid from glucose and CO2 fixation |
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Institution: | 1. School of Bioengineering, Dalian Polytechnic University, Dalian, 116034, China;2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China;3. Division of Solar Energy, Dalian National Laboratory of Clean Energy, Dalian, 116023, China;4. University of Chinese Academy of Sciences, Beijing, 100049, China;5. Dalian Key Laboratory of Energy Biotechnology, Dalian, 116023, China;1. Microbial Biotechnology and Bioprocess Engineering (MBBE) Group, Department of Microbiology, Faculty of Science, University of Maragheh, Maragheh, Iran;2. Department of Biological Science, Faculty of Science, University of Kurdistan, Sanandaj, Iran;3. Department of Microbiology, Faculty of Biological Science, Alzahra University, Tehran, Iran;1. Laboratory of Bioprocess Technology, Department of Microbiology, Maharshi Dayanand University, Rohtak, 124001, Haryana, India;2. Department of Botany, Pt. N.R.S. Govt College, Rohtak, 124001, Haryana, India;3. Department of Biotechnology, Central University of Haryana, Jant-Pali, Mahendergarh, 123031, Haryana, India;1. Fraunhofer Institute of Interfacial and Bioprocess Engineering, Stuttgart, Germany;2. Fraunhofer Center for Chemical-Biotechnological Processes, Leuna, Germany;1. Industrial Bio-materials Research Center, KRIBB, Daejeon 34141, Republic of Korea;2. Department of Biological Sciences, Andong National University, Andong 36729, Republic of Korea;3. Insect Biotech Co. Ltd., Daejeon 34054, Republic of Korea;1. School of Environmental Studies, Jadavpur University, Kolkata 700 032, India;2. Department of Chemistry, Jadavpur University, Kolkata 700 032, India;3. Department of Chemical Engineering, National Institute of Technology, Mahatma Gandhi Road, Durgapur 713 209, India;4. Department of Chemical Engineering, McMaster University, 1280 Main St West, Hamilton, Ontario, L8S 4L8, Canada;1. School of Biochemical Engineering, Pontificia Universidad Católica de Valparaíso (PUCV), Valparaíso, Chile;2. Department of Biology, Faculty of Chemistry and Biology, Universidad de Santiago de Chile (USACH), Santiago, Chile |
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Abstract: | The enzymatic carbon fixation is a promising approach to deal with greenhouse gas emission and is usually accompanied with energy consumption during the reduction of CO2. As a very important route, the carboxylation can convert CO2 to organic carbon without extra requirement of reduction power and is hoped as a greener solution, especially for some non-bulk chemicals, such as medical intermediates. Here, a concept-proof trail of green enzymatic process of conversing both of CO2 and benzene to produce 2,3-dihydroxybenzoic acid (2,3-DHBA), which is the intermediate for fine chemicals, is introduced with O2 from air and glucose. The results showed that the conversion catechol by 2, 3-dihydroxybenzoic acid decarboxylase (2,3-DHBD) alone was around 30 %, with an overall conversion from phenol of 2.4 %, which was limited by the in-situ production of catechol. This trail contributed a green enzymatic route for the production of 2,3-DHBA. |
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Keywords: | 2 3-dihydroxybenzoic acid decarboxylase (2 3-DHBD) Green enzyme reaction route Carboxylation |
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