排序方式: 共有59条查询结果,搜索用时 10 毫秒
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Band Edge Engineering of Oxide Photoanodes for Photoelectrochemical Water Splitting: Integration of Subsurface Dipoles with Atomic‐Scale Control 下载免费PDF全文
Yasuyuki Hikita Kazunori Nishio Linsey C. Seitz Pongkarn Chakthranont Takashi Tachikawa Thomas F. Jaramillo Harold Y. Hwang 《Liver Transplantation》2016,6(7)
One of the crucial parameters dictating the efficiency of photoelectrochemical water‐splitting is the semiconductor band edge alignment with respect to hydrogen and oxygen redox potentials. Despite the importance of metal oxides in their use as photoelectrodes, studies to control the band edge alignment in aqueous solution have been limited predominantly to compound semiconductors with modulation ranges limited to a few hundred mV. The ability to modulate the flat band potential of oxide photoanodes by as much as 1.3 V, using the insertion of subsurface electrostatic dipoles near a Nb‐doped SrTiO3/aqueous electrolyte interface is reported. The tunable range achieved far exceeds previous reports in any semiconductor/aqueous electrolyte system and suggests a general design strategy for highly efficient oxide photoelectrodes. 相似文献
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Self‐Assembled BiFeO3‐ε‐Fe2O3 Vertical Heteroepitaxy for Visible Light Photoelectrochemistry 下载免费PDF全文
Le Thi Quynh Chien Nguyen Van Yugandhar Bitla Jhih‐Wei Chen Thi Hien Do Wen‐Yen Tzeng Sheng‐Chieh Liao Kai‐An Tsai Yi‐Chun Chen Chun‐Lin Wu Chih‐Huang Lai Chih‐Wei Luo Yung‐Jung Hsu Ying‐Hao Chu 《Liver Transplantation》2016,6(18)
Self‐assembled vertical heterostructure with a high interface‐to‐volume ratio offers tremendous opportunities to realize intriguing properties and advanced modulation of functionalities. Here, a heterostructure composed of two visible‐light photocatalysts, BiFeO3 (BFO) and ε‐Fe2O3 (ε‐FO), is designed to investigate its photoelectrochemical performance. The structural characterization of the BFO‐FO heterostructures confirms the phase separation with BFO nanopillars embedded in the ε‐FO matrix. The investigation of band structure of the heterojunction suggests the assistance of photoexcited carrier separation, leading to an enhanced photoelectrochemical performance. The insights into the charge separation are further revealed by means of ultrafast dynamics and electrochemical impedance spectroscopies. This work shows a delicate design of the self‐assembled vertical heteroepitaxy by taking advantage of the intimate contact between two phases that can lead to a tunable charge interaction, providing a new configuration for the optimization of photoelectrochemical cell. 相似文献
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Mohammad Asadi Mohammad Hossein Motevaselian Alireza Moradzadeh Leily Majidi Mohammadreza Esmaeilirad Tao Victor Sun Cong Liu Rumki Bose Pedram Abbasi Peter Zapol Amid P. Khodadoust Larry A. Curtiss Narayana R. Aluru Amin Salehi‐Khojin 《Liver Transplantation》2019,9(9)
Conversion of CO2 to energy‐rich chemicals using renewable energy is of much interest to close the anthropogenic carbon cycle. However, the current photoelectrochemical systems are still far from being practically feasible. Here the successful demonstration of a continuous, energy efficient, and scalable solar‐driven CO2 reduction process based on earth‐abundant molybdenum disulfide (MoS2) catalyst, which works in synergy with an inexpensive hybrid electrolyte of choline chloride (a common food additive for livestock) and potassium hydroxide (KOH) is reported. The CO2 saturated hybrid electrolyte utilized in this study also acts as a buffer solution (pH ≈ 7.6) to adjust pH during the reactions. This study reveals that this system can efficiently convert CO2 to CO with solar‐to‐fuel and catalytic conversion efficiencies of 23% and 83%, respectively. Using density functional theory calculations, a new reaction mechanism in which the water molecules near the MoS2 cathode act as proton donors to facilitate the CO2 reduction process by MoS2 catalyst is proposed. This demonstration of a continuous, cost‐effective, and energy efficient solar driven CO2 conversion process is a key step toward the industrialization of this technology. 相似文献
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Hongzhi Wang Yuying Gao Jia Liu Xinyuan Li Muwei Ji Erhuan Zhang Xiaoyan Cheng Meng Xu Jiajia Liu Hongpan Rong Wenxing Chen Fengtao Fan Can Li Jiatao Zhang 《Liver Transplantation》2019,9(15)
In this communication, light harvesting and photoelectrochemical (PEC) hydrogen generation beyond the visible region are realized by an anisotropic plasmonic metal/semiconductor hybrid photocatalyst with precise control of their topology and heterointerface. Controlling the intended configuration of the photocatalytic semiconductor to anisotropic Au nanorods' plasmonic hot spots, through a water phase cation exchange strategy, the site‐selective overgrowth of a CdSe shell evolving from a core/shell to a nanodumbbell is realized successfully. Using this strategy, tip‐preferred efficient photoinduced electron/hole separation and plasmon enhancement can be realized. Thus, the PEC hydrogen generation activity of the Au/CdSe nanodumbbell is 45.29 µmol cm?2 h?1 (nearly 4 times than the core/shell structure) beyond vis (λ > 700 nm) illumination and exhibits a high faradic efficiency of 96% and excellent stability with a constant photocurrent for 5 days. Using surface photovoltage microscopy, it is further demonstrated that the efficient plasmonic hot charge spatial separation, which hot electrons can inject into CdSe semiconductors, leads to excellent performance in the Au/CdSe nanodumbbell. 相似文献
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Light‐Harvesting Materials: New Light‐Harvesting Materials Using Accurate and Efficient Bandgap Calculations (Adv. Energy Mater. 2/2015) 下载免费PDF全文
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A Sandwich‐Like Organolead Halide Perovskite Photocathode for Efficient and Durable Photoelectrochemical Hydrogen Evolution in Water 下载免费PDF全文
Hefeng Zhang Zhou Yang Wei Yu Hong Wang Weiguang Ma Xu Zong Can Li 《Liver Transplantation》2018,8(22)
Organolead halide perovskite materials have demonstrated great potential in the solar cells field owing to their excellent optoelectronic properties. However, the instability issue of the perovskites impedes the translation of their attractive features for the solar fuel production such as photoelectrochemical H2 production from water splitting. Herein, CH3NH3PbI3 a photocathode with a sandwich‐like structure is fabricated with a general and scalable approach toward addressing this issue. The photocathode exhibits an onset potential at 0.95 V versus reversible hydrogen electrode (RHE) and a photocurrent density of ?18 mA cm?2 at 0 V versus RHE with an impressive ideal ratiometric power‐saved efficiency of 7.63%. More impressively, the photocathode retains good stability under 12 h continuous illumination in water at wide pH range. This performance is much superior to that of the best perovskite‐based photoelectrode ever reported. 相似文献
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Muhibullah Al Mubarok Yuri Choi Rashmi Mehrotra Yu Jin Kim Rama Krishna Boddu Inhui Lee Jiyeong Kim Prof. Sang Kyu Kwak Prof. Ji-Wook Jang Prof. Jungki Ryu Prof. Sung-Yeon Jang 《Liver Transplantation》2024,14(3):2302555
Tin–lead halide perovskites (TLHPs) are promising photoactive materials for photovoltaics (PVs) due to reduced toxicity and broad light absorption. However, their inherent ionic vacancies facilitate inward metal diffusion, accelerating device degradation. Here, efficient, stable TLHP-based PV and photoelectrochemical (PEC) devices are reported containing a chemically protective cathode interlayer—amine-functionalized perylene diimide (PDINN). Solution-processed PDINN effectively extract electrons and suppress inward-metal diffusion by forming tridentate metal complexes with its nucleophilic sites. The PV device achieved an efficiency of 23.21% (>81% retention after 750 h at 60 °C and >90% retention after 3100 h at 23 ± 4 °C), and the first demonstration of TLHP-based PEC devices exhibit a record-high bias-free solar hydrogen production rate (33.0 mA cm−2; ≈3.42 × 10−6 kg s−1 m−2) when coupled with biomass oxidation, which is ≈1.7-fold higher than the ultimate target set by the U.S. Department of Energy for one-sun hydrogen production. These findings demonstrate the potential of TLHPs for efficient, stable photoconversion by the molecular design of the cathode interlayer. 相似文献
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