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1.
Five new ent-pimarane diterpenes ( 1 – 5 ) and five known analogs ( 6 – 10 ) were isolated from the aerial parts of Siegesbeckia pubescens. Their structures, including absolute configurations, were determined by comprehensive spectroscopic methods especially 1D and 2D NMR and quantum chemical electronic circular dichroism calculations. All the isolated compounds were evaluated for their cytotoxicity against human BT549, A549 and H157 cancer cell lines. Among them, compounds 1 and 2 showed mild cytotoxicity against lung cancer cell lines H157 with IC50 values of 16.35±2.59 and 18.86±4.83 μM, respectively. 相似文献
2.
Ferdinand Bohlmann Wolfgang Kramp Jasmin Jakupovic Harold Robinson Robert M. King 《Phytochemistry》1982,21(2):399-403
The aerial parts of Baccharis minutiflora afforded in addition to known compounds eight new ent-kaurane derivatives, one being a homo kaurane, while the aerial parts of B. alatemoides gave two pairs of epimeric clerodane derivatives, which, however, had to be modified chemically before they could be separated. The stereochemistry of these diterpenes could not be elucidated with certainty. 相似文献
3.
A series of unstable mono- and di-esters of the tetracyclic diterpene ingenol were isolated from the pro-inflammatory ether-soluble fraction of the latex of Euphorbia kamerunica. The esters were isolated by a neutral process involving column and thin-layer chromatography. The monoesters were identified by spectroscopic methods and hydrolysis reactions as ingenol-3-decanoate, ingenol-3-dodecanoate, ingenol-5-hexadienoate and ingenol-5-octenoate and the diesters as 20-acetyl-ingenol-3-octenoate and 20-acetyl-ingenol-3-angelate. 相似文献
4.
Alessandro Ballio Renato Capasso Antonio Evidente Giuliano Grandolini Giacomino randazzo 《Phytochemistry》1982,21(7):1810-1811
The stereostructure of cotylenol, the aglycone of the cotylenins, has been confirmed by chemical correlation with the aglycone of fusicoccin A. 相似文献
5.
Ferdinand Bohlmann Maniruddin Ahmed Jasmin Jakupovic Robert M. King Harold Robinson 《Phytochemistry》1982,21(3):691-694
An investigation of Brickellia diffusa afforded three new dehydronerolidol derivatives and five new labdane derivatives, all highly oxygenated. The structures were elucidated by spectroscopic methods and a few chemical transformations. The compounds isolated showed close relationships to those isolated from Brickellia sp. 相似文献
6.
From three Mikania species, three new labdanic acid and two kaurenic acid derivatives have been isolated together with known compounds and four new germacranolides, differing only in the ester moiety. 相似文献
7.
Eszter Gács-Baitz Lajos Radics G.B. Oganessian Vilen A. Mnatsakanian 《Phytochemistry》1978,17(11):1967-1973
The structure and stereochemistry of teucrins H1, H2, H3 and H4, four novel diterpenes from Teucrium hyrcanicum have been established by detailed studies of the PMR and 13C NMR spectra, CD results and chemical transformations. Teucrin H4, a minor constituent is shown to possess a unique stereochemistry hitherto not reported for related diterpenoids. 相似文献
8.
Ferdinand Bohlmann Christa Zdero Wolf-Rainer Abraham Antoinette Suwita Michael Grenz 《Phytochemistry》1980,19(5):873-879
The investigation of 25 further Helichrysum species afforded in addition to known compounds a new diterpene, an oxo-geranyllinalol, a second one, most probably a cembrene derivative, and three dihydrochalkone derivatives. The distribution of the constituents in South African Helichrysum species is discussed briefly. 相似文献
9.
From the acetone and ethanol extracts of the tubercula of Aristolochia pubescens, two diterpene esters of aristolochic acids were isolated, together with 23 known compounds. The structures of the compounds were determined on the basis of spectroscopic analysis. 相似文献
10.
Ferdinand Bohlmann Jasmin Jakupovic Robert M. King Harold Robinson 《Phytochemistry》1981,20(7):1613-1622
The aerial parts of L. santosii afforded three new diterpenes, a phenylpropanol, three eudesmane derivatives, three germacranolides, seventeen guaianolides and four rearranged guaianolides of a, so far, unknown type. Furthermore, several known compounds were isolated. The structures of the new compounds, the separations of which caused difficulties, were elucidated by spectroscopic methods and by some chemical transformations. The chemotaxonomic situation is discussed briefly. 相似文献