全文获取类型
收费全文 | 1562篇 |
免费 | 57篇 |
国内免费 | 39篇 |
出版年
2023年 | 19篇 |
2022年 | 18篇 |
2021年 | 28篇 |
2020年 | 34篇 |
2019年 | 38篇 |
2018年 | 32篇 |
2017年 | 32篇 |
2016年 | 22篇 |
2015年 | 32篇 |
2014年 | 37篇 |
2013年 | 80篇 |
2012年 | 29篇 |
2011年 | 42篇 |
2010年 | 40篇 |
2009年 | 33篇 |
2008年 | 54篇 |
2007年 | 68篇 |
2006年 | 41篇 |
2005年 | 60篇 |
2004年 | 41篇 |
2003年 | 45篇 |
2002年 | 29篇 |
2001年 | 20篇 |
2000年 | 19篇 |
1999年 | 30篇 |
1998年 | 12篇 |
1997年 | 19篇 |
1996年 | 22篇 |
1995年 | 9篇 |
1994年 | 21篇 |
1993年 | 17篇 |
1992年 | 11篇 |
1991年 | 20篇 |
1990年 | 13篇 |
1989年 | 19篇 |
1987年 | 15篇 |
1985年 | 49篇 |
1984年 | 43篇 |
1983年 | 22篇 |
1982年 | 38篇 |
1981年 | 35篇 |
1980年 | 54篇 |
1979年 | 41篇 |
1978年 | 36篇 |
1977年 | 33篇 |
1976年 | 34篇 |
1975年 | 48篇 |
1974年 | 48篇 |
1973年 | 49篇 |
1972年 | 17篇 |
排序方式: 共有1658条查询结果,搜索用时 31 毫秒
91.
92.
The structure of a new bisindole alkaloid, 12′-hydroxyisostrychnobiline, has been proposed from the analysis of its 300 MHz 1H NMR spectrum and comparison of the spectroscopic data with those of various monomeric and dimeric alkaloids, previously isolated from the same Strychnos species 相似文献
93.
Carmen Alicia Peña 《Phytochemistry》1979,18(8):1419-1420
94.
A reverse-phase high-performance liquid chromatography method utilizing evaporative light scattering detection (ELSD) has been developed for the simultaneous detection of hepatotoxic pyrrolizidine alkaloids with and without chromophores, namely, riddelliine, riddelliine N-oxide, senecionine, senecionine N-oxide, seneciphylline, retrorsine, integerrimine, lasiocarpine and heliotrine. Pyrrolizidine alkaloids were detected in five plant extracts (Senecio spartioides, S. douglasii var. longilobus, S. jacobaea, S. intergerrimus var. exaltatus and Symphytum officinale). The detection of heliotrine (which does not contain a chromophore) was much improved by ELSD compared with photodiode array detection. 相似文献
95.
96.
Two new venalstonine derivatives, viz., venacarpines A and B, and one new dioxokopsan derivative, kopsorinine, in addition to the kopsifolines A-F, and 11 other known alkaloids, were isolated from a Malayan Kopsia species. The structures of the new alkaloids were determined using NMR and MS analysis. 相似文献
97.
Two strains of Agrobacterium rhizogenes (15834, LBA 9402) and one Agrobacterium tumefaciens strain [GV 3101 (PMP90RK, p35SGUS-2)] and four culture media were tested and compared for their ability to induce hairy root formation on wounded Papaver somniferum L. hypocotyls. Five weeks after the infection with A. rhizogenes LBA 9402, hairy roots appeared on 80% of the hypocotyls maintained in the hormone-free liquid medium. Six hairy-root cultures were established. Transformation was confirmed by polymerase chain reaction analysis. One clone was analysed for its alkaloid production. The total alkaloid content was higher in the transformed roots (0.46±0.06% DW) than in the untransformed roots (0.32±0.05% DW). The transformed roots accumulated three times more codeine (0.18±0.02% DW) than intact roots (0.05±0% DW). Moreover, morphine (0.255±0.03% DW) and sanguinarine (0.014±0% DW) were found in the liquid culture medium.Abbreviations
2,4-D
2,4-Dichlorophenoxyacetic acid
-
LS
Linsmaier and Skoog 相似文献
98.
99.
The ability of 19 microorganisms to perform the enantioselective lactonization of racemic gamma,delta-epoxy ester 3a and its 7-methyl homolog 3b was checked. It was found that Rhodotorula rubra preferentialy transformed both substrates to (-)-enantiomers of trans delta-hydroxy-gamma-lactones with ee 76% for 3a and 24% for 3b. The best efficiency (20-30%) and enantioselectivity (ee 60-100%) of formation of (-)-gamma-hydroxy-delta-lactones 6a and 6b was observed for lactonization by Botrytis cinerea and Fusarium semitectum, respectively. 相似文献
100.
In various environments where primates are presently observed, as well as in forests and savannas which have been inhabited by australopithecines and early hominids, there are (or there have been presumably) categories of substances eliciting taste signals associated with stereotyped responses. Such is the case for various soluble sugars of fruits and nectars, attracting consumers, and for several plant compounds in which bitter or strongly astringent properties have a repulsive effect. The occurrence of such classes of tasty substances among natural products appears to be related to the evolutionary trends that shaped primate sensory perception (for detecting either beneficent or potentially noxious substances) in the context of a long history of coevolution between animals and plants. Here, we present original psychophysical data on humans (412 individuals aged 17-59 years) as an analogy with which to test recent evidence from electrophysiology in nonhuman primates (Hellekant et al. [1997] J. Neurophysiol. 77:978-993; Danilova et al. [1998] Ann. N.Y. Acad. Sci. 855:160-164) that taste fibers can be grouped into clusters of "best-responding fibers" with two more specific clusters, one for sugars and one for quinine and tannins. The collinearity found between human taste responses (recognition thresholds) for fructose and sucrose, as well as for quinine and tannins, is presented and discussed as another evidence of the two-direction evolutionary trend determining taste sensitivity. Salt perception appears to be totally independent of these trends. Accordingly, the appreciation of a salty taste seems to be a recent culturally learned response, and not a primary taste perception. The very existence of primary tastes is discussed in the context of evolutionary trends, past and present. 相似文献