全文获取类型
收费全文 | 347篇 |
免费 | 99篇 |
国内免费 | 9篇 |
出版年
2024年 | 9篇 |
2023年 | 20篇 |
2022年 | 15篇 |
2021年 | 8篇 |
2020年 | 17篇 |
2019年 | 18篇 |
2018年 | 25篇 |
2017年 | 31篇 |
2016年 | 32篇 |
2015年 | 30篇 |
2014年 | 20篇 |
2013年 | 19篇 |
2012年 | 13篇 |
2011年 | 21篇 |
2010年 | 10篇 |
2009年 | 10篇 |
2008年 | 6篇 |
2007年 | 24篇 |
2006年 | 9篇 |
2005年 | 6篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 8篇 |
2001年 | 5篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 9篇 |
1995年 | 1篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1974年 | 1篇 |
排序方式: 共有455条查询结果,搜索用时 156 毫秒
21.
Jingxiang Pang Meina Yang Jialei Fu Xiaolei Zhao Eduard van Wijk Mei Wang Yanli Liu Xiaoyan Zhou Hua Fan Jinxiang Han 《Luminescence》2016,31(2):491-498
Traditional Chinese material medica are an important component of the Chinese pharmacopeia. According to the traditional Chinese medicinal concept, Chinese herbal medicines are classified into different categories based on their therapeutic effects, however, the bioactive principles cannot be solely explained by chemical analysis. The aim of this study is to classify different Chinese herbs based on their therapeutic effects by using delayed luminescence (DL). The DL of 56 Chinese herbs was measured using an ultra‐sensitive luminescence detection system. The different DL parameters were used to classify Chinese herbs according to a hierarchical cluster analysis. The samples were divided into two groups based on their DL kinetic parameters. Interestingly, the DL classification results were quite consistent with classification according to the Chinese medicinal concepts of ‘cold’ and ‘heat’ properties. In this paper, we show for the first time that by using DL technology, it is possible to classify Chinese herbs according to the Chinese medicinal concept and it may even be possible to predict their therapeutic properties. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
22.
Paweena Chuenwarin Azumi Shimazaki Masanori Shimizu Yuko Kobayashi Masakazu Katsumata 《Bioscience, biotechnology, and biochemistry》2016,80(3):452-460
Nondestructive evaluation of photosynthesis is a valuable tool in the field and laboratory. Delayed luminescence (DL) can reflect charge recombination through the backflow of electrons. However, DL detection has not yet been adapted for whole plants in Petri dishes. To compensate for differences in DL decay between sibling Arabidopsis plants grown under the same conditions, we developed a time-sequential double measurement method. Using this method, we examined the influence of photosynthetic electron flow inhibitors, and differences in the DL decay curves were categorized by considering the initial and late phases of the decay curves, as well as their intermediate slopes. The appearance of concavity and convexity in DL curves in Arabidopsis was different from unicellular algae, suggesting complexity in the photosynthetic machinery of higher plants. This detection method should be invaluable for evaluating photosynthetic defects in higher plants under sterile conditions without interrupting plant culture. 相似文献
23.
构建由脂肪乳剂和墨水组成的皮肤组织模型,定量研究皮肤组织模型的吸收系数μa和散射系数μs对光敏化单线态氧(singlet oxygen,~1O_2)发光特性的影响。利用~1O_2发光检测系统测量含光敏剂四硫磺基酞菁氯化铝的皮肤组织模型分别在中心波长为1 230,1 270和1 310 nm处的时间分辨发光光谱,对扣除背景信号后的时间分辨~1O_2发光光谱进行积分和拟合,获得~1O_2发光积分强度以及激发三重态寿命τ_T和~1O_2寿命τ_D。结果表明在皮肤组织模型中,~1O_2发光积分强度随着μ_a和μ_s的增大而减小,μ_a对τ_T和τ_D没有影响。τ_T随着μs的增加而增加,τ_D随μ_s的增加先骤降而后缓慢上升。当μ_a1.5 mm~(-1)和μ_s32 cm~(-1)时,~1O_2发光积分强度和τ_T、τ_D均趋于稳定,其中τ_T和τ_D分别为3.4±0.6μs和3.3±0.7μs。 相似文献
24.
25.
Boyi Chen Jun Peng Heping Shen The Duong Daniel Walter Steve Johnston Mowafak M. Al‐Jassim Klaus J. Weber Thomas P. White Kylie R. Catchpole Daniel Macdonald Hieu T. Nguyen 《Liver Transplantation》2019,9(7)
A fast, nondestructive, camera‐based method to capture optical bandgap images of perovskite solar cells (PSCs) with micrometer‐scale spatial resolution is developed. This imaging technique utilizes well‐defined and relatively symmetrical band‐to‐band luminescence spectra emitted from perovskite materials, whose spectral peak locations coincide with absorption thresholds and thus represent their optical bandgaps. The technique is employed to capture relative variations in optical bandgaps across various PSCs, and to resolve optical bandgap inhomogeneity within the same device due to material degradation and impurities. Degradation and impurities are found to both cause optical bandgap shifts inside the materials. The results are confirmed with micro‐photoluminescence spectroscopy scans. The excellent agreement between the two techniques opens opportunities for this imaging concept to become a quantified, high spatial resolution, large‐area characterization tool of PSCs. This development continues to strengthen the high value of luminescence imaging for the research and development of this photovoltaic technology. 相似文献
26.
Zhenyu Gao Lixin Yu Xiaoqin Man Jianlin Zhong Qihuang Guo Yingxuan Zou 《Luminescence》2019,34(8):830-837
The MgO–Ga2O3–SiO2 glasses and glass‐ceramics samples doped with Eu2+/Mn2+/Er3+ and heated in reductive atmosphere were prepared by the sol–gel method. The structure, morphology and the luminescence properties were studied using X‐ray diffraction, high‐resolution transmission electron microscope, fluorescence spectra, and up‐conversion emission. The luminescence characteristics of doped ions could be influenced by temperature and matrix component. The characteristic emission of Mn2+, Eu2+ and Er3+ were seen and the energy transfer efficiency from Eu2+ to Mn2+ was enhanced as Mn2+ concentration was increased. In addition, the two‐photon process was determined for the Er3+‐doped samples. 相似文献
27.
Nicholas C. Davy Marius Koch Guy Olivier Ngongang Ndjawa Xin Lin Gabriel J. Man YunHui L. Lin Jeni C. Sorli Barry P. Rand Antoine Kahn Gregory D. Scholes Yueh‐Lin Loo 《Liver Transplantation》2019,9(48)
The electron–hole recombination kinetics of organic photovoltaics (OPVs) are known to be sensitive to the relative energies of triplet and charge‐transfer (CT) states. Yet, the role of exciton spin in systems having CT states above 1.7 eV—like those in near‐ultraviolet‐harvesting OPVs—has largely not been investigated. Here, aggregation‐induced room‐temperature intersystem crossing (ISC) to facilitate exciton harvesting in OPVs having CT states as high as 2.3 eV and open‐circuit voltages exceeding 1.6 V is reported. Triplet excimers from energy‐band splitting result in ultrafast CT and charge separation with nonradiative energy losses of <250 meV, suggesting that a 0.1 eV driving force is sufficient for charge separation, with entropic gain via CT state delocalization being the main driver for exciton dissociation and generation of free charges. This finding can inform engineering of next‐generation active materials and films for near‐ultraviolet OPVs with open‐circuit voltages exceeding 2 V. Contrary to general belief, this work reveals that exclusive and efficient ISC need not require heavy‐atom‐containing active materials. Molecular aggregation through thin‐film processing provides an alternative route to accessing 100% triplet states on photoexcitation. 相似文献
28.
Nguyen Mai Cao Hoang Phuong Lan Pham Van Huan Nguyen Huu Thong Duy-Hung Nguyen Nguyen Duc Trung Kien Chu Manh Nhuong Cao Xuan Thang Vuong-Hung Pham 《Luminescence》2022,37(4):577-587
A series of Mn2+-doped zinc germinate ZGO:xMn2+ (x = 0–0.05) nanorods was synthesized successfully using a hydrothermal method. XRD revealed that crystal phases of the ZGO:xMn2+ were rhombohedral and in the R-3 space group. The Williamson–Hall equation was also used to explain the strain, nanocrystalline size, and stacking fault. Green LEDs were successfully fabricated by coating ZGO:Mn2+ nanorods onto UV-LED chips. For high color purity, CIE of the fabricated green LEDs were (0.2404, 0.5428), which made this material a promising candidate for fabrication of UV-based green LEDs. 相似文献
29.
The article briefly reports the fundamental scientific principles and landmarks in the field of luminescence and further enlightens the importance of persistent phosphor that is now widely used in luminous paints. Its main focus is on phosphorescence that makes use of lanthanides that have gained paramount importance in various cross-sections of luminescent applications. Both inorganic and organic afterglow materials, synthesis and characterization along with skilled researchers' essential updates on emerging trends and efforts are elucidated at length. It exclusively reviews the red/green/blue organic/inorganic/hybrid phosphorescent materials and the latest advances in the development of novel long afterglow materials that can accelerate the green technology in the world of luminescence. 相似文献
30.
Circularly polarized luminescence of Sm (III) and Eu (III) complexes with chiral ligand (R/S)‐BINAPO
Luminescent lanthanide (III) ions have been exploited for circularly polarized luminescence (CPL) for decades. However, very few of these studies have involved chiral samarium (III) complexes. Complexes are prepared by mixing axial chiral ligands (R/S))‐2,2’‐bis(diphenylphosphoryl)‐1,1′‐binaphthyl (BINAPO) with europium and samarium Tris (trifluoromethane sulfonate) (Eu (OTf)3 and Sm (OTf)3). Luminescence‐based titration shows that the complex formed is Ln((R/S)‐BINAPO)2(OTf)3, where Ln = Eu or Sm. The CPL spectra are reported for Eu((R/S)‐BINAPO)2(OTf)3 and Sm((R/S)‐BINAPO)2(OTf)3. The sign of the dissymmetry factors, gem, was dependent upon the chirality of the BINAPO ligand, and the magnitudes were relatively large. Of all of the complexes in this study, Sm((S)‐BINAPO)2(OTf)3 has the largest gem = 0.272, which is one of the largest recorded for a chiral Sm3+ complex. A theoretical three‐dimensional structural model of the complex that is consistent with the experimental observations is developed and refined. This report also shows that (R/S)‐BINAPO are the only reported ligands where gem (Sm3+) > gem (Eu3+). 相似文献