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171.
Gaojie Xu Chunguang Pang Bingbing Chen Jun Ma Xiao Wang Jingchao Chai Qingfu Wang Weizhong An Xinhong Zhou Guanglei Cui Liquan Chen 《Liver Transplantation》2018,8(9)
In this paper, tris(trimethylsilyl) phosphite (TMSP) and 1,3‐propanediolcyclic sulfate (PCS) are unprecedentedly prescribed as binary functional additives for treating the poor performances of high‐voltage (5 V‐class) LiNi0.5Mn1.5O4/MCMB (graphitic mesocarbon microbeads) Li‐ion batteries at both room temperature and 50 °C. The high‐voltage LiNi0.5Mn1.5O4/MCMB cell with binary functional additives shows a preponderant discharge capacity retention of 79.5% after 500 cycles at 0.5 C rate at room temperature. By increasing the current intensity from 0.2 to 5 C rate, the discharge capacity retention of the high‐voltage cell with binary functional additives is ≈90%, while the counterpart is only ≈55%. By characterizations, it is rationally demonstrated that the binary functional additives decompose and participate in the modification of solid–electrolyte interface layers (both electrodes), which are more conductive, protective, and resistant to electrolyte oxidative/reductive decompositions (accompanying active‐Li+ consuming parasitic reactions) due to synergistic effects. Specifically, the TMSP additive can stabilize LiPF6 salt and scavenge erosive hydrofluoric acid. More encouragingly, at 50 °C, the high‐voltage cell with binary functional additives holds an ultrahigh discharge capacity retention of 79.5% after 200 cycles at 1 C rate. Moreover, a third designed self‐extinguishing flame‐retardant additive of (ethoxy)‐penta‐fluoro‐cyclo‐triphosphazene (PFPN) is introduced for reducing the flammability of the aforementioned binary functional additives containing electrolyte. 相似文献
172.
Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite‐Free Lithium Metal Anode Current Collector
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Heng Zhao Danni Lei Yan‐Bing He Yifei Yuan Qinbai Yun Bin Ni Wei Lv Baohua Li Quan‐Hong Yang Feiyu Kang Jun Lu 《Liver Transplantation》2018,8(19)
The development of lithium (Li) metal anodes Li metal batteries faces huge challenges such as uncontrolled Li dendrite growth and large volume change during Li plating/stripping, resulting in severe capacity decay and high safety hazards. A 3D porous copper (Cu) current collector as a host for Li deposition can effectively settle these problems. However, constructing a uniform and compact 3D porous Cu structure is still an enormous challenge. Herein, an electrochemical etching method for Cu–Zinc (Zn) alloy is reported to precisely engrave a 3D Cu structure with uniform, smooth, and compact porous network. Such a continuous structure endows 3D Cu excellent mechanical properties and high electrical conductivity. The uniform and smooth pores with a large internal surface area ensures well dispersed current density for homogeneous Li metal deposition and accommodation. A smooth and stable solid electrolyte interphase is formed and meanwhile Li dendrites and dead Li are effectively suppressed. The Li metal anode conceived 3D Cu current collector can stably cycle for 400 h under an Li plating/stripping capacity of 1 mA h cm?2 and a current density of 1 mA cm?2. The Li@3D Cu||LiFePO4 full cells present excellent cycling and rate performances. The electrochemical dealloying is a robust method to construct 3D Cu current collectors for dendrite‐free Li metal anodes. 相似文献
173.
Design and Performance of Rechargeable Sodium Ion Batteries,and Symmetrical Li‐Ion Batteries with Supercapacitor‐Like Power Density Based upon Polyoxovanadates
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Jia‐Jia Chen Jian‐Chuan Ye Xia‐Guang Zhang Mark D. Symes Shao‐Cong Fan De‐Liang Long Ming‐Sen Zheng De‐Yin Wu Leroy Cronin Quan‐Feng Dong 《Liver Transplantation》2018,8(6)
The polyanion Li7V15O36(CO3) is a nanosized molecular cluster (≈1 nm in size), that has the potential to form an open host framework with a higher surface‐to‐bulk ratio than conventional transition metal oxide electrode materials. Herein, practical rechargeable Na‐ion batteries and symmetric Li‐ion batteries are demonstrated based on the polyoxovanadate Li7V15O36(CO3). The vanadium centers in {V15O36(CO3)} do not all have the same VIV/V redox potentials, which permits symmetric devices to be created from this material that exhibit battery‐like energy density and supercapacitor‐like power density. An ultrahigh specific power of 51.5 kW kg?1 at 100 A g?1 and a specific energy of 125 W h kg?1 can be achieved, along with a long cycling life (>500 cycles). Moreover, electrochemical and theoretical studies reveal that {V15O36(CO3)} also allows the transport of large cations, like Na+, and that it can serve as the cathode material for rechargeable Na‐ion batteries with a high specific capacity of 240 mA h g?1 and a specific energy of 390 W h kg?1 for the full Na‐ion battery. Finally, the polyoxometalate material from these electrochemical energy storage devices can be easily extracted from spent electrodes by simple treatment with water, providing a potential route to recycling of the redox active material. 相似文献
174.
Black Phosphorus Quantum Dot/Ti3C2 MXene Nanosheet Composites for Efficient Electrochemical Lithium/Sodium‐Ion Storage
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Ruijin Meng Jimei Huang Yutong Feng Lianhai Zu Chengxin Peng Lirong Zheng Lei Zheng Zhibin Chen Guanglei Liu Bingjie Chen Yongli Mi Jinhu Yang 《Liver Transplantation》2018,8(26)
The exploration of new and efficient energy storage mechanisms through nanostructured electrode design is crucial for the development of high‐performance rechargeable batteries. Herein, black phosphorus quantum dots (BPQDs) and Ti3C2 nanosheets (TNSs) are employed as battery and pseudocapacitive components, respectively, to construct BPQD/TNS composite anodes with a novel battery‐capacitive dual‐model energy storage (DMES) mechanism for lithium‐ion and sodium‐ion batteries. Specifically, as a battery‐type component, BPQDs anchored on the TNSs are endowed with improved conductivity and relieved stress upon cycling, enabling a high‐capacity and stable energy storage. Meanwhile, the pseudocapacitive TNS component with further atomic charge polarization induced by P? O? Ti interfacial bonds between the two components allows enhanced charge adsorption and efficient interfacial electron transfer, contributing a higher pseudocapacitive value and fast energy storage. The DMES mechanism is evidenced by substantial characterizations of X‐ray photoelectron spectroscopy and X‐ray absorption fine structure spectroscopy, density functional theory calculations, and kinetics analyses. Consequently, the composite electrode exhibits superior battery performance, especially for lithium storage, such as high capacity (910 mAh g?1 at 100 mA g?1), long cycling stability (2400 cycles with a capacity retention over 100%), and high rate capability, representing the best comprehensive battery performance in BP‐based anodes to date. 相似文献
175.
Entesar Dalah An Tai Kiyoko Oshima William A Hall Beth Erickson X. Allen Li 《Translational oncology》2018,11(5):1104-1109
PURPOSE: Performance of anatomical metrics of Response Evaluation Criteria in Solid Tumors (RECIST1.1) versus Positron Emission Tomography Response Criteria in Solid Tumors (PERCIST1.0) for neoadjuvant chemoradiation (nCR) of pancreatic adenocarcinoma was evaluated based on the pathological treatment response (PTR) data. METHODS AND MATERIALS: The pre- and post-nCR CT and PET data for 14 patients with resectable or borderline resectable pancreatic head adenocarcinoma treated with nCR followed by surgery were retrospectively analyzed. These data were compared with the PTR which were graded according to tumor cell destruction (cellularity), with Grade 0, 1, 2 or 3 (G0, G1, G2 or G3) for complete, moderate, minimal and poor responses, respectively. Maximum standardized uptake value (SUVmax) was defined using body-weight (SUVbw). PERCIST1.0 was defined using lean-body mass normalized SUV (SUVlb or SUL). RECIST1.1 was defined by contouring the whole pancreas head on the CT image. Pre- and post-SUL-peak and SUVmax, RECIST1.1 and PETRECIST1.0 were correlated with PTR using Pearson’s correlation coefficient test. RESULTS: The average mean and SD in SUL-peak for all patients analyzed were lower in post-nCR (3.63±1.06) compared to those at pre-nCR (4.29±0.89). Using PERCIST1.0, 62% of patients showed stable metabolic disease (SMD), 23% partial metabolic response (PMR), and 15% progressive metabolic disease (PMD). Using RECIST1.1, 85% of patients showed stable disease (SD), 8% partial response (PR), and 7% progressive diseases (PD). A poor insignificant correlation was established between PRT and PERECIST1.0 (r=0.121), whereas no correlation was seen with RECIST1.1. CONCLUSIONS: PERCIST1.0 appears to increase the chance of detecting patients with progressive disease compared to the conventional anatomical-based assessment of RECIST1.1. The integration of these additional radiographic metrics in assessing treatment response to nCR for pancreatic adenocarcinoma may provide a promising strategy to better select patients that are most suitable for therapeutic intensification. 相似文献
176.
蒲桃Syzygium jambos(L)Alston叶上的类葡柄菌属Stemphyliomma Saccardo &Traverso—新种定名为异色类葡柄菌Stemphyliomma heterochomum N Li & Zhao sp.nov.,对该种形态作了汉、拉文描述,并绘图示之。模式标本保存在西南林学院(HSFC)森林病理标本室(HSFC 941279)。 相似文献
177.
李济先生与周口店研究:纪念李济先生诞辰100周年 总被引:1,自引:0,他引:1
李济先生是中国考古学的奠基人,中国第一位人类学家。他毕生从事考古学研究,著作等身,桃李满天下。他的功绩主要体现在安阳殷墟的发掘与研究上,考古学的其他方面亦建树甚丰。本文仅就李先生在中国旧石器考古草创时期,特别是在周口店本世纪30年代初发掘方法改革中的贡献等方面作简要的介绍。以此纪念济先生诞辰100周年。为使读者了解他取得巨大成就的历史背景,对其生平亦作点录。 相似文献
178.
本文报道了采自我国新疆阿勒泰山寄生于蔷薇科(Rosaceae)植物地榆(Sanguisorba officinalis L.)上的轴霜霉新种——地榆轴霜霉(Plasmopara Sanguisorbae C.J.Li et al.sp.nov.)。轴霜霉寄生于蔷薇科植物上是首次报道。对该种的形态作了拉丁文和汉文描述,并附有特征图。 相似文献
179.
180.
Tuning Transition Metal Oxide–Sulfur Interactions for Long Life Lithium Sulfur Batteries: The “Goldilocks” Principle
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Xiao Liang Chun Yuen Kwok Fernanda Lodi‐Marzano Quan Pang Marine Cuisinier He Huang Connor J. Hart Diane Houtarde Kavish Kaup Heino Sommer Torsten Brezesinski Jürgen Janek Linda F. Nazar 《Liver Transplantation》2016,6(6)
The lithium‐sulfur battery is a compelling energy storage system because its high theoretical energy density exceeds Li‐ion batteries at much lower cost, but applications are thwarted by capacity decay caused by the polysulfide shuttle. Here, proof of concept and the critical metrics of a strategy to entrap polysulfides within the sulfur cathode by their reaction to form a surface‐bound active redox mediator are demonstrated. It is shown through a combination of surface spectroscopy and cyclic voltammetry studies that only materials with redox potentials in a targeted window react with polysulfides to form active surface‐bound polythionate species. These species are directly correlated to superior Li‐S cell performance by electrochemical studies of high surface area oxide cathodes with redox potentials below, above, and within this window. Optimized Li‐S cells yield a very low fade rate of 0.048% per cycle. The insight gained into the fundamental surface mechanism and its correlation to the stability of the electrochemical cell provides a bridge between mechanistic understanding and battery performance essential for the design of high performance Li‐S cells. 相似文献