Current issues in the characterisation of toxicological impacts

Fate, exposure and effect measures provide a basis for the calculation of characterisation factors in Life Cycle Assessment (LCA). Such characterisation factors provide insights into the relative concern of chemical emissions within and across life cycle inventories, in the context of toxicological stress to humans and to ecosystems. A brief overview is presented in this paper of the available options for toxicological characterisation and of associated issues that will need to be addressed in future consensus-building initiatives. An introduction is provided to issues such as: (1) the benefit of measures calculated at midpoints versus at endpoints in the toxicological cause-effect chains (sometimes termed environmental mechanisms); (2) the need to use multimedia models with spatial resolution; (3) the political consequences of accounting for variations in population density; (4) uncertainties in the toxicological potency measures; and (5) the different options for the toxicological endpoint measure(s). These issues are addressed under the headings of Fate and Exposure, Human Health and (aquatic) Ecosystem Health.     

Development of damage function for stratospheric ozone layer depletion

The purpose of our study was to develop damage functions due to ozone layer depletion, that related the emission of ozone depleting substances (ODS) to the damage of category endpoints. The ozone layer depletion causes many types of damage such as skin cancer, cataract, adverse effect to crop and plant growth. We assessed the increase of skin cancer incidence risk. The damage function have been developed with connecting the main processes on ozone depletion, emission of ODS, increase of tropospheric ODS, increase of stratospheric ODS, change of total ozone, change of B region ultra-violet (UV-B) at the surface, and the increase of skin cancer incidence. As the result, we could introduce damage functions of melanoma and non-melanoma skin cancer incidence for 13 species of ODSs and damage factors based on the disability-adjusted life years (DALYs). We also compared the DALYs value with the damage factors of Eco-indicator 99 (egalitarian and hierarchic value), and it was found that our result was several ten times as small except methyl bromide. Furthermore, a case study for refrigerator was performed and it showed that shifting to less ozone depleting substances reduced the risk of skin cancer incidence to one-fourteenth in DALYs.     

The Importance of Normalization References in Interpreting Life Cycle Assessment Results

A normalization step is widely exercised in life cycle assessment (LCA) studies in order to better understand the relative significance of impact category results. In the normalization stage, normalization references (NRs) are the characterized results of a reference system, typically a national or regional economy. Normalization is widely practiced in LCA‐based decision support and policy analysis (e.g., LCA cases in municipal solid waste treatment technologies, renewable energy technologies, and environmentally preferable purchasing programs, etc.). The compilation of NRs demands significant effort and time as well as an intimate knowledge of data availability and quality. Consequently only one set of published NRs is available for the United States, and has been adopted by various studies. In this study, the completeness of the previous NRs was evaluated and significant data gaps were identified. One of the reasons for the significant data gaps was that the toxic release inventory (TRI) data significantly underestimate the potential impact of toxic releases for some sectors. Also the previous NRs did not consider the soil emissions and nitrogen (N) and phosphorus (P) runoffs to water and chemical emissions to soils. Filling in these data gaps increased the magnitude of NRs for “human health cancer,” “human health noncancer,” “ecotoxicity,” and “eutrophication” significantly. Such significant changes can alter or even reverse the outcome of an LCA study. We applied the previous and updated NRs to conventional gasoline and corn ethanol LCAs. The results demonstrate that NRs play a decisive role in the interpretation of LCA results that use a normalization step.     

IMPACT 2002+: A new life cycle impact assessment methodology

The new IMPACT 2002+ life cycle impact assessment methodology proposes a feasible implementation of a combined midpoint/damage approach, linking all types of life cycle inventory results (elementary flows and other interventions) via 14 midpoint categories to four damage categories. For IMPACT 2002+, new concepts and methods have been developed, especially for the comparative assessment of human toxicity and ecotoxicity. Human Damage Factors are calculated for carcinogens and non-carcinogens, employing intake fractions, best estimates of dose-response slope factors, as well as severities. The transfer of contaminants into the human food is no more based on consumption surveys, but accounts for agricultural and livestock production levels. Indoor and outdoor air emissions can be compared and the intermittent character of rainfall is considered. Both human toxicity and ecotoxicity effect factors are based on mean responses rather than on conservative assumptions. Other midpoint categories are adapted from existing characterizing methods (Eco-indicator 99 and CML 2002). All midpoint scores are expressed in units of a reference substance and related to the four damage categories human health, ecosystem quality, climate change, and resources. Normalization can be performed either at midpoint or at damage level. The IMPACT 2002+ method presently provides characterization factors for almost 1500 different LCI-results, which can be downloaded at http://www.epfl.ch/impact     

The Design of a Sustainability Assessment Standard Using Life Cycle Information

Sustainability assessment standards are currently being developed for a range of building products. This activity has been stimulated through the considerable success of the U.S. Green Building Council's (USGBC) LEED? standard. Transparent life cycle–based standards can guide manufacturers to design products that have reduced environmental impact. The use of a sustainability standard can certify performance and avoid green washing. In this article we present a logical framework for designing a sustainability assessment standard through the creation of tables that award points in the standard to be consistent with life cycle information. Certain minimum principles of consistency are articulated. In the case that the life cycle impact assessment method maps the life cycle inventory to impact through a linear weighting, two design approaches—impact category and activity substitution—are constructed to be consistent with these principles. The approach is illustrated in a case study of a partial redesign of a carpet sustainability assessment standard (NSF/ANSI‐140).     

Anaerobic digestion of starch-polyvinyl alcohol biopolymer packaging: biodegradability and environmental impact assessment

The digestibility of a starch-polyvinyl alcohol (PVOH) biopolymer insulated cardboard coolbox was investigated under a defined anaerobic digestion (AD) system with key parameters characterized. Laboratory results were combined with industrial operational data to develop a site-specific life cycle assessment (LCA) model. Inoculated with active bacterial trophic groups, the anaerobic biodegradability of three starch-PVOH biopolymers achieved 58-62%. The LCA modeling showed that the environmental burdens of the starch-PVOH biopolymer packaging under AD conditions on acidification, eutrophication, global warming and photochemical oxidation potential were dominated by atmospheric emissions released from substrate degradation and fuel combustion, whereas energy consumption and infrastructure requirements were the causes of abiotic depletion, ozone depletion and toxic impacts. Nevertheless, for this bio-packaging, AD of the starch-PVOH biopolymer combined with recycling of the cardboard emerged as the environmentally superior option and optimization of the energy utilization system could bring further environmental benefits to the AD process.     

Occupational health impacts: offshore crane lifts in life cycle assessment

Background, Aim, and Scope  The identification and assessment of environmental tradeoffs is a strongpoint of life cycle assessment (LCA). A tradeoff made in many product systems is the exchange of potential for occupational accidents with the additional use of energy and materials. Net benefits of safety measures with respect to human health are best illustrated if the consequences avoided and health impacts induced by additional emissions are assessed using commensurable metrics. Our aim is to develop a human health impact indicator for offshore crane lifts. Crane lifts are a major cause of accidents on offshore oil and gas (O & G) rigs, and health impacts from crane lift accidents should be included in comparative LCA of O & G technologies if the alternatives differ in the use of crane lifts. Materials and methods  Accident records for mobile offshore petroleum installations were used to develop an empirical occupational health indicator for crane lifts in LCA. Probabilistic parameters were introduced in the procedure, and results were calculated by Monte Carlo simulation. The disability adjusted life years (DALY) framework was used to classify health outcome. The characterization factor for offshore crane lifts was applied in three comparisons to evaluate the significance of crane lifts to human health impacts from drilling technology. Results  The mean occupational health impact per crane lift was 4.5∙10⁻⁶ DALY, with cumulative percentiles {P _2.5, P ₅₀, P _97.5} = {6.0∙10⁻⁷, 3.1∙10⁻⁶, 1.7∙10⁻⁵}. Analogously, the fatal accident frequency was described by {P _2.5, P ₅₀, P _97.5} = {7.6∙10⁻⁹, 3.9∙10⁻⁸, 2.0∙10⁻⁷}, with mean 5.6∙10⁻⁸ lives lost per crane lift. Discussion  The uncertainty in the results is caused mainly by the random nature of accidents, i.e., variability in accident frequency. Applications of the characterization factor indicate that although crane lifts may not be significant to the overall health impact of the life cycle of drilling fluids, they are important to the occupational safety of employees on offshore drilling rigs and contribute significantly to the life cycle health impact of loading technologies used to transport drilling waste to shore. A comparative LCA of technologies for loading and off-loading drilling wastes shows that a recently developed hydraulic system performs better than the traditional crane lift alternative in terms of human health impacts. Conclusions  With the availability of statistics to assess the risk of single mechanical operations, safety aspects may well be included in LCA. For the case of offshore crane lifts, the uncertainty in the characterization factor compares favorably to what is indicated for other human health impact chains. In further work of quantifying occupational health impacts in DALY using accident statistics, it is advised to see if records of non-recoverable injuries (fatalities and amputation cases) can be used to simplify the damage assessment procedure as recoverable injuries were insignificant to the total burden from crane accidents. Recommendations and perspectives  The characterization factor for crane lifts identifies contributions to life cycle health impact from loading technologies that otherwise would have been overlooked in LCA. While many contest the inclusion of occupational accidents in LCA, our results show that such impacts can be included and that their consideration adds valuable insights.     

Philosophy of science, policy sciences and the basis of decision support with LCA Based on the toxicity controversy in Sweden and the Netherlands

Current LCA implicitly assumes that a single rational truth can be found. Mainstream policy sciences has taken a different starting point when analysing decision making in complex and controversial societal debates for already several decades. In such debates, in general, more than one reasonable conceptualisation or ‘framing’ of the problem is at stake which forms the core of the controversy. This paper analyses the Dutch chlorine debate and the Swedish PVC debate and shows that (three) frames also play a role in toxicity controversies: the risk assessment frame, the strict control frame, and the precautionary frame. The latter frame, adhered to by the environmentalists, seeks to judge substances mainly on their inherent safety. The cases show that this logic may be defended as at least being equally reasonable to the emission-effect calculations that form the core of Risk Assessment and Life-cycle Impact Assessment (LCIA). As predicted by policy sciences, this finding implies that the political neutrality of tools like LCIA is questionable. In summary, the approaches and procedures developed for LCA have to be reconciled with key lessons from policy science and philosophy of science, i.e. considering the fact that multiple realities play a key role in many decision making processes. This paper suggests some alternative indicators for toxicity evaluations, and indicates the implications of LCA method development.     

Exploring the Use of Ecological Footprint in Life Cycle Impact Assessment

Ecological footprint (EF) is a metric that estimates human consumption of biological resources and products, along with generation of waste greenhouse gas (GHG) emissions in terms of appropriated productive land. There is an opportunity to better characterize land occupation and effects on the carbon cycle in life cycle assessment (LCA) models using EF concepts. Both LCA and EF may benefit from the merging of approaches commonly used separately by practitioners of these two methods. However, few studies have compared or integrated EF with LCA. The focus of this research was to explore methods for improving the characterization of land occupation within LCA by considering the EF method, either as a complementary tool or impact assessment method. Biofuels provide an interesting subject for application of EF in the LCA context because two of the most important issues surrounding biofuels are land occupation (changes, availability, and so on) and GHG balances, two of the impacts that EF is able to capture. We apply EF to existing fuel LCA land occupation and emissions data and project EF for future scenarios for U.S. transportation fuels. We find that LCA studies can benefit from lessons learned in EF about appropriately modeling productive land occupation and facilitating clear communication of meaningful results, but find limitations to the EF in the LCA context that demand refinement and recommend that EF always be used along with other indicators and metrics in product‐level assessments.