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1.
Mary M. Sherman Robert P. Borris Masaru Ogura Geoffrey A. Cordell Norman R. Farnsworth 《Phytochemistry》1980,19(7):1499-1501
A new triterpene has been isolated from the root bark of Ailanthus excelsa (Simaroubaceae) and identified as 3S,24S,25-trihydroxytirucall-7-ene. 相似文献
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The component hydrocarbons, sterols, alcohols, monobasic, α,ω-dibasic and ω-hydroxy acids of the fresh hand decayed leaves and the pneumatophores of the mangrove Avicennia marina are reported in detail. From the quantitative comparisons which can be drawn, relative changes in the lipid classes occurring during leaf decay can be highlighted. These base-line data are important to our understanding of inputs to marine intertidal sediments. During leaf decay the only significant changes were a reduction in the total absolute concentrations of monobasic acids due largely to a decrease in concentration of the C18 polyunsaturated fatty acids, and an enhancement of the concentrations of the long-chain monobasic acids, ω-hydroxy acids and α,ω-dibasic acids. This resistance to degradation shown by the cutin derived acids (α,ω-dibasic, ω-hydroxy and long-chain monobasic acids) relative to the cellular and wax derived lipids may allow these cutin components to be used as quantitative markers of A. marina in mangrove associated sediments. 相似文献
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《Bioscience, biotechnology, and biochemistry》2013,77(11):2278-2282
Aleuritopteris ferns produce triterpenes and sesterterpenes with tricyclic cheilanthane and tetracyclic 18-episcalarane skeletons. The structural and mechanistic similarities between both classes of fern terpene suggest that their biosynthetic enzymes may be closely related. We investigate here whether a triterpene synthase is capable of recognizing geranylfarnesols as a substrate, and is able to convert them to cyclic sesterterpenes. We found that a bacterial triterpene synthase converted all-E-geranylfarnesol (1b) into three scalarane sesterterpenes with 18αH stereochemistry (5, 7 and 8), as well as mono- and tricyclic sesterterpenes (6 and 9). In addition, 2Z-geranylfarnesol (4) was converted into an 18-episcalarane derivative (10), whose skeleton can be found in sesterterpenes isolated from Aleuritopteris ferns. These results provide insight into sesterterpene biosynthesis in Aleuritopteris ferns. 相似文献
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《Bioscience, biotechnology, and biochemistry》2013,77(10):1732-1734
A new oleanane triterpene was isolated from okara fermented with Penicillium simplicissimum ATCC 90288. Its structure was established to be 7β, 15α,24-trihydroxyolean-12-en-3,11,22-trione by spectroscopic techniques and an X-ray crystaliographic analysis. 相似文献
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Shohei Takase Kota Kera Yuya Hirao Tsutomu Hosouchi Yuki Kotake Yoshiki Nagashima 《Bioscience, biotechnology, and biochemistry》2019,83(2):251-261
Cucurbitaceae plants contain characteristic triterpenoids. Momordica charantia, known as a bitter melon, contains cucurbitacins and multiflorane type triterpenes, which confer bitter tasting and exhibit pharmacological activities. Their carbon skeletons are biosynthesized from 2,3-oxidosqualene by responsible oxidosqualene cyclase (OSC). In order to identify OSCs in M. charantia, RNA-seq analysis was carried out from ten different tissues. The functional analysis of the resulting four OSC genes revealed that they were cucurbitadienol synthase (McCBS), isomultiflorenol synthase (McIMS), β-amyrin synthase (McBAS) and cycloartenol synthase (McCAS), respectively. Their distinct expression patterns based on RPKM values and quantitative RT-PCR suggested how the characteristic triterpenoids were biosynthesized in each tissue. Although cucurbitacins were finally accumulated in fruits, McCBS showed highest expression in leaves indicating that the early step of cucurbitacins biosynthesis takes place in leaves, but not in fruits.
Abbreviations: OSC: oxidosqualene cyclase; RPKM: reads perkilobase of exon per million mapped reads 相似文献