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In this work, we simulate the microphase separation of aqueous and non-aqueous solutions of diblock copolymer poly(styrene)-b-poly(ethyleneglycol) under different architectures (linear and linear–dendritic) by dissipative particle dynamics. The observed morphologies in water where poly(ethyleneglycol) (PEG) block is soluble are as follows: (1) at low concentrations spherical micelles, cylinders and bicontinuous structures are formed in dendritic structures and spheres, cylinders and perforated lamellas in linear structure. The architectures simulated at low–moderate concentrations show an evolution sphere → cylinder → bicontinuous or perforated lamellas as the concentration is increased. (2) At high concentrated solutions rich defect structures of the sponge type are formed. In a non-aqueous non-polar solution such as cyclohexane, which is a good solvent for the polystyrene block, the formation of well-defined aggregates at low concentrations is not observed; however, irregular structures are achieved in concentrated solutions. We compare these results with a polymeric chimera consisting of a mixture of linear poly(styrene) homopolymer and PEG homopolymer in the linear, G1 or G2 dendritic configurations. Our simulations are in agreement with the experimentally observed structures of these polymers. 相似文献
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