A 15N nuclear magnetic resonance study of the biosynthesis of quinoxaline antibiotics

Uniformly ¹⁵N-labelled triostin A and echinomycin have been prepared by growing the producing organisms on enriched media and their ¹⁵N nuclear magnetic resonance spectra partially assigned by a combination of nuclear Overhauser effect and scalar coupling constant measurements. Selective feeding experiments using unlabelled L-tryptophan-supplemented media have shown that N-1 and N-4 of the quinoxaline rings have their origins in the indole and amino groups of tryptophan, respectively.     

The anaerobic decomposition of benzoic acid during methane fermentation

Anaerobic rupture of the benzoic acid ring was investigated. Carbon 4 was converted primarily to carbon dioxide. Following ring rupture during methane fermentation, propanoic acid is an intermediate, and carbon 4 of benzoate becomes its carboxyl.Contribution No. 1285-j, Division of Biology, Kansas State University, Manhattan, KS 66506. This work was supported in part by funds from the Kansas Agricultural Experiment Station, Kansas State University, Manhattan, KS 66506. Paper II of this series is Fina and Fiskin (1960)     

PRODUCTIVITY AND PRODUCTION EFFICIENCY OF AN UPPER SONORAN DESERT EPHEMERAL COMMUNITY

During years with good winter rainfall, ephemeral plants can contribute considerably to primary production in the upper Sonoran Desert. This study was designed to compare ephemeral community productivity and production efficiency within the different microhabitats created by trees, shrubs and open spaces in a Sonoran Desert ecosystem. Ephemerals were periodically harvested in the different habitats and dried for biomass and caloric determinations. The caloric data were compared to total solar input into the different microhabitats in order to determine production efficiencies of each stand. Productivity rates were also determined for the total community for the sample period, winters of 1972-74. Both productivity and production efficiency were highest under the shade of Cercidium. The highest production efficiency occurring in the shaded sites was 5.03% which approaches the theoretical maximum photosynthetic efficiency level. The production efficiency of the entire ephemeral community for the whole growing season was only 0.17% during an optimal year, demonstrating the influence of the environment in the interspaces on productivity and solar conversion in the desert.