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11.
Lester A. Mitscher Sitaraghav R. Gollapudi Ish K. Khanna Steven D. Drake T. Hanumaiah T. Ramaswamy Kolluru V. Jagannadha Rao 《Phytochemistry》1985,24(12):2885-2887
Flemiflavanone-D from Flemingia stricta is active in vitro against Staphylococcus aureus and Mycobacterium smegmatis. Reexamination and interpretation of its spectral properties required revision of its molecular formula to C25H28O6 and its structure to 2S-5,7,4′-trihydroxy-6-γ,γ-dimethylallyl-3′-γ,γ-dimethylallyl-oxidoflavan-4-one. The new structure was confirmed when reaction with chlorotrimethylsilane sodium iodide in acetonitrile deoxygenated and cyclized flemiflavanone-D to the known dicycloeuchrestaflavanone A. The absolute stereochemistry of flemiflavanone-D was established to be 2S by circular dichroism measurements. 相似文献
12.
Sridhara Babu Pepalla Subba Rao Jammula Hanumaiah Telikepalli Kesava Rao Bhattiprolu Kolluru Venkata Jagannadha Rao 《Phytochemistry》1991,30(12):4193-4194
A new naphthalene glucoside lactone was isolated from the acetone extract of the stem bark of Rhamnus wightii. Cynodontin, chrysophanol, physcion, musizin, lupeol, sitosterol, 7-hydroxy-5-methoxyphthalide, emodin, sitosterol glycoside, β-sorigenin are the known compounds; β-sorigenin may be an artifact of its glucoside. The co-occurrence of two lactone ring compounds, 7-hydroxy-5-methoxyphthalide and the naphthalide glucoside is the significant feature of this plant. 相似文献